Applying multi-scale silica-like three-dimensional networks in PEO matrix via in-situ crosslinking for high-performance solid composite electrolyte

Author(s):  
Jiawei Wu ◽  
Jing Chen ◽  
Xiaodong Wang ◽  
An'an Zhou ◽  
Zhenglong Yang

For the higher safety and energy density, solid-state electrolyte with better mechanical strength, thermal and electrochemical stability is a perfect choice. To improve the performance of PEO, usage of low-cost...

2017 ◽  
Vol 5 (20) ◽  
pp. 9960-9969 ◽  
Author(s):  
Sheng Zhu ◽  
Zidan Wang ◽  
Fangzhi Huang ◽  
Hui Zhang ◽  
Shikuo Li

Well-aligned hierarchical Cu(OH)2@Ni2(OH)2CO3 core/shell nanowire arrays in situ grown on conductive copper foams as binder- and conductive-free electrodes display superior electrochemical performances.


RSC Advances ◽  
2019 ◽  
Vol 9 (72) ◽  
pp. 42183-42193 ◽  
Author(s):  
Qiushi Sun ◽  
Xiao Chen ◽  
Jian Xie ◽  
Xiongwen Xu ◽  
Jian Tu ◽  
...  

A nonflammable quasi-solid-state composite electrolyte was prepared by in situ polymerization for safe, stable Li metal batteries.


Author(s):  
Shuyuan Li ◽  
Nianwu Li ◽  
Chunwen Sun

A quasi-solid-state electrolyte based on LATP-PVDF-HFP nanofiber matrix and gel is proposed. The fabricated battery exhibits a good discharge capacity of 146.6 mA h g−1 at 2C, while the capacity retention can reach 97% after 300 cycles at 0.5C.


Author(s):  
Kathryn Holguin ◽  
Motahareh Mohammadiroudbari ◽  
Kaiqiang Qin ◽  
Chao Luo

Na-ion batteries (NIBs) are promising alternatives to Li-ion batteries (LIBs) due to the low cost, abundance, and high sustainability of sodium resources. However, the high performance of inorganic electrode materials...


Author(s):  
Marcel Simsek ◽  
Nongnoot Wongkaew

AbstractNon-enzymatic electrochemical sensors possess superior stability and affordability in comparison to natural enzyme-based counterparts. A large variety of nanomaterials have been introduced as enzyme mimicking with appreciable sensitivity and detection limit for various analytes of which glucose and H2O2 have been mostly investigated. The nanomaterials made from noble metal, non-noble metal, and metal composites, as well as carbon and their derivatives in various architectures, have been extensively proposed over the past years. Three-dimensional (3D) transducers especially realized from the hybrids of carbon nanomaterials either with metal-based nanocatalysts or heteroatom dopants are favorable owing to low cost, good electrical conductivity, and stability. In this critical review, we evaluate the current strategies to create such nanomaterials to serve as non-enzymatic transducers. Laser writing has emerged as a powerful tool for the next generation of devices owing to their low cost and resultant remarkable performance that are highly attractive to non-enzymatic transducers. So far, only few works have been reported, but in the coming years, more and more research on this topic is foreseeable. Graphical abstract


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 946
Author(s):  
Qianyi Yang ◽  
Fuqiang Lu ◽  
Yulin Liu ◽  
Yijie Zhang ◽  
Xiujuan Wang ◽  
...  

Solid electrolytes with high Li-ion conductivity and electrochemical stability are very important for developing high-performance all-solid-state batteries. In this work, Li2(BH4)(NH2) is nanoconfined in the mesoporous silica molecule sieve (SBA-15) using a melting–infiltration approach. This electrolyte exhibits excellent Li-ion conduction properties, achieving a Li-ion conductivity of 5.0 × 10−3 S cm−1 at 55 °C, an electrochemical stability window of 0 to 3.2 V and a Li-ion transference number of 0.97. In addition, this electrolyte can enable the stable cycling of Li|Li2(BH4)(NH2)@SBA-15|TiS2 cells, which exhibit a reversible specific capacity of 150 mAh g−1 with a Coulombic efficiency of 96% after 55 cycles.


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