Fully π-conjugated, diyne-linked covalent organic frameworks formed via alkyne-alkyne cross-coupling reaction
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A novel diyne-linked porphyrin-based COF was constructed through palladium catalyzed alkyne-alkyne coupling for the first time. The new material features inherent porosity, moderate crystallinity, excellent durability, full π-conjugation, and can...
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2020 ◽
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