Chemoselective Reduction of α,β-Unsaturated Ketones to Allylic Alcohols Under Catalyst-Free Conditions

2022 ◽  
Author(s):  
Kaixia Jian ◽  
Bingnan Li ◽  
Shuxian Zhu ◽  
Qingqing Xuan ◽  
Qiuling Song
Keyword(s):  
Precious Metals ◽  
Allylic Alcohols ◽  
Unsaturated Ketones ◽  
Catalyst Free

Chemoselective reductions of α, β-unsaturated ketones to afford the corresponding allylic alcohols have always been challenging. Precious metals and ligands have always been employed in these transformations. Herein, we described...

Divergent Functionalization of α,β-Enones: Catalyst-free Access to β-Azido Ketones and β-Amino α-Diazo Ketones

2021 ◽  
Author(s):  
Youshao Tu ◽  
honglin Dong ◽  
Huamin Wang ◽  
Yuhui Ao ◽  
Yu Liu
Keyword(s):  
Carbonyl Compounds ◽  
Practical Method ◽  
Free Access ◽  
Unsaturated Ketones ◽  
Catalyst Free

A simple and practical method for the azidation of β-fluoroalkyl α,β-unsaturated ketones to access a wide variety of fluorinated nitrogenous carbonyl compounds is developed. Different from existing precedents, neither metallic...

Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction of γ,δ-unsaturated ketones

2015 ◽  
Vol 51 (57) ◽  
pp. 11512-11514 ◽  
Author(s):  
Shu-Jie Chen ◽  
Guo-Ping Lu ◽  
Chun Cai
Keyword(s):  
Allylic Alcohols ◽  
Unsaturated Ketones ◽  
Efficient Construction ◽  
Decarboxylative Allylation

A highly regioselective protocol is reported for the efficient construction of γ,δ-unsaturated ketones from β-ketoacids and allylic alcohols.

Chemoselective Reduction of Complexα,β-Unsaturated Ketones to Allylic Alcohols over Ir-Metal Particles onβ Zeolites

2003 ◽  
Vol 42 (43) ◽  
pp. 5333-5336 ◽  
Author(s):  
Mario De bruyn ◽  
Simona Coman ◽  
Roxana Bota ◽  
Vasile I. Parvulescu ◽  
Dirk E. De Vos ◽  
...  
Keyword(s):  
Metal Particles ◽  
Allylic Alcohols ◽  
Unsaturated Ketones

The Mechanism of Oxidation of Allylic Alcohols to α,β-Unsaturated Ketones by Cytochrome P450†

1996 ◽  
Vol 9 (5) ◽  
pp. 871-874 ◽  
Author(s):  
Giuseppe Bellucci ◽  
Cinzia Chiappe ◽  
Laura Pucci ◽  
Pier Giovanni Gervasi
Keyword(s):  
Cytochrome P450 ◽  
Allylic Alcohols ◽  
Unsaturated Ketones ◽  
Mechanism Of Oxidation
Sign in / Sign up

Export Citation Format

Share Document