Borane-Catalyzed Cascade Friedel-Crafts Alkylation/[1,5]-Hydride Transfer/Mannich Cyclization to Afford Tetrahydroquinolines

Chemical Science ◽

10.1039/d1sc05629h ◽

2022 ◽

Author(s):

Bei-Bei Zhang ◽

Shuo Peng ◽

Feiyi Wang ◽

Cuifen Lu ◽

Junqi Nie ◽

...

Keyword(s):

Hydride Transfer ◽

Mannich Cyclization

An unprecedented redox-neutral annulation of tertiary anilines with electron-deficient alkynes was developed that proceeds through a cascade Friedel-Crafts alkylation/[1,5]-hydride transfer/Mannich cyclization sequence. Under B(C6F5)3 catalysis, a range of functionalized 1,2,3,4-tetrahydroquinolines...

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Faculty Opinions recommendation of Quantum dynamics of hydride transfer catalyzed by bimetallic electrophilic catalysis: synchronous motion of Mg(2+) and H(-) in xylose isomerase.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1007975.100509 ◽

2002 ◽

Author(s):

Mark Nelson

Keyword(s):

Quantum Dynamics ◽

Hydride Transfer ◽

Xylose Isomerase ◽

Synchronous Motion

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Faculty Opinions recommendation of Barriers to Hydride Transfer in Wild Type and Mutant Dihydrofolate Reductase from E. coli.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1016691.201160 ◽

2003 ◽

Author(s):

Arieh Warshel

Keyword(s):

Dihydrofolate Reductase ◽

Hydride Transfer ◽

Wild Type ◽

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Faculty Opinions recommendation of Lactate Racemase Nickel-Pincer Cofactor Operates by a Proton-Coupled Hydride Transfer Mechanism.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.732770883.793543614 ◽

2018 ◽

Author(s):

Michael Maroney

Keyword(s):

Hydride Transfer ◽

Transfer Mechanism

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Hydride transfer stereospecificity of rat liver aldehyde dehydrogenases.

Journal of Biological Chemistry ◽

10.1016/s0021-9258(18)60901-9 ◽

1987 ◽

Vol 262 (23) ◽

pp. 10911-10913

Author(s):

K H Jones ◽

R Lindahl ◽

D C Baker ◽

R Timkovich

Keyword(s):

Rat Liver ◽

Hydride Transfer ◽

Aldehyde Dehydrogenases

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Computational study on the mechanism of hydroboration of CO2 catalysed by POCOP pincer nickel thiolate complexes: concerted catalysis and hydride transfer by a shuttle

Dalton Transactions ◽

10.1039/d0dt04345a ◽

2021 ◽

Vol 50 (8) ◽

pp. 2903-2914

Author(s):

Nana Ma ◽

Chenhao Tu ◽

Qingli Xu ◽

Wenyue Guo ◽

Jie Zhang ◽

...

Keyword(s):

Computational Study ◽

Hydride Transfer ◽

Dft Computations ◽

Thiolate Complexes

The concerted catalysis and hydride shuttle mechanism for pincer nickel thiolate catalysed hydroboration of CO2 was established by DFT computations.

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The Mechanism of Sugar C−H Bond Oxidation by a Flavoprotein Oxidase Occurs by a Hydride Transfer Before Proton Abstraction

Chemistry - A European Journal ◽

10.1002/chem.201806078 ◽

2019 ◽

Vol 25 (17) ◽

pp. 4460-4471 ◽

Author(s):

Thanyaporn Wongnate ◽

Panida Surawatanawong ◽

Litavadee Chuaboon ◽

Narin Lawan ◽

Pimchai Chaiyen

Keyword(s):

Hydride Transfer ◽

Proton Abstraction

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Active site arginine controls the stereochemistry of hydride transfer in cyclohexanone monooxygenase

Archives of Biochemistry and Biophysics ◽

10.1016/j.abb.2018.09.025 ◽

2018 ◽

Vol 659 ◽

pp. 47-56 ◽

Author(s):

Osei Boakye Fordwour ◽

Kirsten R. Wolthers

Keyword(s):

Active Site ◽

Hydride Transfer ◽

Cyclohexanone Monooxygenase

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Structure–Reactivity Effects on Intrinsic Primary Kinetic Isotope Effects for Hydride Transfer Catalyzed by Glycerol-3-phosphate Dehydrogenase

Journal of the American Chemical Society ◽

10.1021/jacs.6b07028 ◽

2016 ◽

Vol 138 (44) ◽

pp. 14526-14529 ◽

Author(s):

Archie C. Reyes ◽

Tina L. Amyes ◽

John P. Richard

Keyword(s):

Isotope Effects ◽

Hydride Transfer ◽

Kinetic Isotope Effects ◽

Kinetic Isotope ◽

Glycerol 3 Phosphate Dehydrogenase

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Barriers to Hydride Transfer in Wild Type and Mutant Dihydrofolate Reductase fromE.coli

The Journal of Physical Chemistry B ◽

10.1021/jp035734n ◽

2003 ◽

Vol 107 (50) ◽

pp. 14042-14051 ◽

Author(s):

Ian F. Thorpe ◽

Charles L. Brooks

Keyword(s):

Dihydrofolate Reductase ◽

Hydride Transfer ◽

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Stereochemistry of asymmetric “(net) hydride transfer” in an intercoenzyme model reaction system

Tetrahedron Letters ◽

10.1016/s0040-4039(00)78456-5 ◽

1994 ◽

Vol 35 (46) ◽

pp. 8631-8634 ◽

Author(s):

Tetsuji Kawamoto ◽

Toru Taga ◽

Kiyoshi Bessho ◽

Fumio Yoneda ◽

Jun-ichi Hayami

Keyword(s):

Reaction System ◽

Hydride Transfer ◽

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