Panchromatic Terthiophenyl-benzodithiophene Conjugated Porphyrin Donor for Efficient Organic Solar Cells

Author(s):  
Wei Tang ◽  
Liping Xie ◽  
Zhixin Liu ◽  
Jie Zeng ◽  
Xuan Zhou ◽  
...  

Two intermediate-sized acceptor-π-porphyrin-π-acceptor type molecules MPor1 and MPor2 with panchromatic absorption were here presented toward improved photovoltaic property. A breakthrough of absorption spectrum to cover the gap between Soret and...

2021 ◽  
pp. 2109735
Author(s):  
Hao Ren ◽  
Yunlong Ma ◽  
Hui‐Min Liu ◽  
Jing‐De Chen ◽  
Ye‐Fan Zhang ◽  
...  

Author(s):  
Keli Shi ◽  
Beibei Qiu ◽  
Can Zhu ◽  
Xinxin Xia ◽  
Xiaonan Xue ◽  
...  

To deeply investigate the structure-property relationship in organic solar cells (OSCs), one widely used strategy is to design a series of organic photovoltaic materials with same chemical formular but different...


2018 ◽  
Vol 3 (1) ◽  
pp. 131-141 ◽  
Author(s):  
Yan Zou ◽  
Yue Wu ◽  
Hang Yang ◽  
Yingying Dong ◽  
Chaohua Cui ◽  
...  

The engineering of alkylthio side chains in the molecular conjugated backbone of small molecules is in favor of achieving a linear molecular backbone conformation, slightly red-shifting the absorption spectrum, and down-shifting the HOMO energy level of the resulting molecule.


2018 ◽  
Vol 54 (3) ◽  
pp. 303-306 ◽  
Author(s):  
Junhui Miao ◽  
Bin Meng ◽  
Jun Liu ◽  
Lixiang Wang

The use of an A–D–A′–D–A strategy to develop small molecule acceptors with broad absorption spectra through suppressing the intramolecular charge transfer effect is studied.


2016 ◽  
Vol 6 (21) ◽  
pp. 1601001 ◽  
Author(s):  
Alyssa N. Brigeman ◽  
Michael A. Fusella ◽  
Yixin Yan ◽  
Geoffrey E. Purdum ◽  
Yueh-Lin Loo ◽  
...  

Author(s):  
Antoine Goujon ◽  
Lou Rocard ◽  
Thomas Cauchy ◽  
Piétrick Hudhomme

AzaBenzannulated PDI (AzaBPDI) dyes were synthesized in high yields via a new reaction sequence involving an imine condensation followed by visible light-induced photocyclization. The large scope and efficiency of this alternative to the Pictet-Spengler reaction is demonstrated, and allows the easy preparation of dimeric AzaBPDI as potential non-fullerene acceptors for organic solar cells.


2019 ◽  
Author(s):  
Matthew Morgan ◽  
Maryam Nazari ◽  
Thomas Pickl ◽  
J. Mikko Rautiainen ◽  
Heikki M. Tuononen ◽  
...  

The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron-nitrogen doped dihydroindeno[1,2-<i>b</i>]fluorene which can be synthesized via mildly air-sensitive techniques and the end products handled readily under atmosphereic conditions. Through transmetallation via diarylzinc reagents a series of derivatives were sythesized which show broad absorption profiles that highlight the versatility of this backbone to be used in organic solar cell devices. These compounds can be synthesized in large yields, in alow number of steps and functionalized at many stages along the way providing a large depth of possibilities. Exploratory device paramaters were studied and show PCE of 2%.


2019 ◽  
Author(s):  
Enrique Pascual-San-José ◽  
Xabier Rodríguez-Martínez ◽  
Fei Zhuping ◽  
Martin Heeney ◽  
Roger Guimerà-Manrique ◽  
...  

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