Ruthenium complexes containing Group 5B donor ligands. Part 8. Reactions of binuclear carbonyl- and thiocarbonyl-ruthenium(II) triphenylphosphine complexes with alkoxy(phenyl)phosphines and of mononuclear ruthenium(II) alkoxy(phenyl)phosphine complexes with carbon monoxide

1979 ◽  
pp. 1045 ◽  
Author(s):  
Wilma J. Sime ◽  
T. Anthony Stephenson
Keyword(s):  
Carbon Monoxide ◽  
Ruthenium Complexes ◽  
Donor Ligands ◽  
Phosphine Complexes

Neutral η6-arene ruthenium complexes with monodentate P-donor ligands

2012 ◽  
Vol 363-364 ◽  
pp. 49-57 ◽  
Author(s):  
Arnald Grabulosa ◽  
Alberto Mannu ◽  
Elisabetta Alberico ◽  
Stefania Denurra ◽  
Serafino Gladiali ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Donor Ligands

Ruthenium complexes containing group 5b donor ligands

1978 ◽  
Vol 161 (3) ◽  
pp. 391-406 ◽  
Author(s):  
P.W. Armit ◽  
W.J. Sime ◽  
T.A. Stephenson ◽  
L. Scott
Keyword(s):  
Ruthenium Complexes ◽  
Donor Ligands

Sterically demanding methoxy and methyl groups in ruthenium complexes lead to enhanced quantum yields for blue light triggered photodissociation

2018 ◽  
Vol 47 (44) ◽  
pp. 15685-15693 ◽  
Author(s):  
Fengrui Qu ◽  
Kristina Martinez ◽  
Ashley M. Arcidiacono ◽  
Seungjo Park ◽  
Matthias Zeller ◽  
...  
Keyword(s):  
Blue Light ◽  
Ruthenium Complexes ◽  
Donor Ligands ◽  
Quantum Yields ◽  
Methyl Groups ◽  
Sterically Demanding ◽  
The Impact

Ruthenium complexes exhibit enhanced photodissociation quantum yields due to bulky, weak donor ligands, illustrating the impact of electronics and sterics.

Reactions of carbonyl and nitrosyl ruthenium complexes with uninegative (X,S)-donor ligands (X = S, P)

Polyhedron ◽  
1991 ◽  
Vol 10 (10) ◽  
pp. 1019-1023 ◽  
Author(s):  
A. Gutierrez-Alonso ◽  
L. Ballester-Reventos
Keyword(s):  
Ruthenium Complexes ◽  
Donor Ligands

Studies of β-Diketone Complexes of Rhenium. VIII. The Reaction of β-Diketones with Chloropentacarbonylrhenium(I), and the Preparation of Complexes of the Type Re(CO)4(dik), Re2(CO)6(dik)2, Re2(CO)6Cl2(dikH)2, Re(CO)3L(dik), and Re(CO)2(dik)L2

1975 ◽  
Vol 53 (16) ◽  
pp. 2481-2489 ◽  
Author(s):  
Maurice Conrad Fredette ◽  
Colin James Lyne Lock
Keyword(s):  
Carbon Monoxide ◽  
High Pressure ◽  
Infrared Spectroscopy ◽  
Mass Spectroscopy ◽  
Vibrational Spectra ◽  
Donor Ligands

The reaction of β-diketones with Re(CO)5Cl gave compounds of stoichiometries Re2(CO)6dik2 or Re2Cl2(CO)6(dikH)2. Reaction of the former compounds with carbon monoxide at high pressure gave Re(CO)4.dik, while with donor ligands such as pyridine or triphenylphosphine they gave compounds of stoichiometry Re(CO)3dikL. With triphenylphosphine further reaction gave Re(CO)2dik[P(C6H5)3]2. Compounds were investigated by infrared spectroscopy and mass spectroscopy, and a Cotton–Kraihânzel analysis was made of the carbonyl vibrational spectra in order to get an estimate of the π-acceptor ability of the β-ketoenolate ligands.

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