Application of time-dependent rate constant theory to reactions of solvated electrons. Reaction distances, rate constants and diffusion coefficients in concentrated aqueous solutions

1975 ◽  
Vol 71 (0) ◽  
pp. 115 ◽  
Author(s):  
George V. Buxton ◽  
Frank C. R. Cattell ◽  
Frederick S. Dainton
Keyword(s):  
Aqueous Solutions ◽  
Rate Constant ◽  
Rate Constants ◽  
Diffusion Coefficients ◽  
Time Dependent ◽  
Solvated Electrons ◽  
Concentrated Aqueous Solutions ◽  
Dependent Rate ◽  
And Diffusion

scholarly journals Mechanistic Investigations of an α-Aminoarylation Photoredox Reaction

2021 ◽  
Author(s):  
Bernard Stevenson ◽  
Ethan Spielvogel ◽  
Emily Loiaconi ◽  
Victor M. Wambua ◽  
Roman Nakhamiyayev ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Absorption Spectroscopy ◽  
Rate Constant ◽  
Kinetic Modeling ◽  
Rate Constants ◽  
Transient Absorption ◽  
Coupling Reaction ◽  
Time Dependent ◽  
Transient Absorption Spectroscopy ◽  
Mechanistic Investigations

We present time-dependent percent and quantum yield measurements of a photoredox-catalyzed coupling reaction between 1,4-dicyanobenzene and N-phenylpyrrolidine. We also use transient absorption spectroscopy to examine the kinetics within the reaction and use kinetic modeling to extract rate constants and predict how changes in rate constant will impact the quantum yield.

A new time-dependent rate constant of the coalescence kernel for the modelling of fluidised bed granulation

2021 ◽  
Vol 379 ◽  
pp. 321-334
Author(s):  
Kevin Cronin ◽  
Francisco J. Gutiérrez Ortiz ◽  
Denis Ring ◽  
Fuweng Zhang
Keyword(s):  
Rate Constant ◽  
Time Dependent ◽  
Fluidised Bed ◽  
Dependent Rate ◽  
New Time

Ionic conductivities and diffusion coefficients of alkyl substituted sulfonated resorcinarenes in aqueous solutions

2019 ◽  
Vol 133 ◽  
pp. 223-228 ◽  
Author(s):  
Diana M. Galindres ◽  
Ana C.F. Ribeiro ◽  
Artur J.M. Valente ◽  
Miguel A. Esteso ◽  
Edilma Sanabria ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Diffusion Coefficients ◽  
Ionic Conductivities ◽  
And Diffusion
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