Exchange reactions and magnetic susceptibilities of complex salts. Part III. Exchange reactions of some nickel complex salts

Author(s):  
H. C. Clark ◽  
A. L. Odell
1963 ◽  
Vol 18 (3) ◽  
pp. 349-356 ◽  
Author(s):  
Hanako Kobayashi ◽  
Taiichiro Haseda ◽  
Eizo Kanda ◽  
Seiichi Kanda

1948 ◽  
Vol 45 ◽  
pp. 147-149 ◽  
Author(s):  
C. C. Evans ◽  
S. Sugden

Author(s):  
Alexander S. Lelekov ◽  
Rudolf P. Trenkenshu

The paper presents an example of the linear splines use to describe the photosynthesis light curves for microalgae culture. The main mathematical models of the relationship between photosynthesis rate and light are listed. Based on the previously formulated basic principles of modeling microalgae photobiosynthesis, a mathematical model is proposed that describes the dependence of the assimilation number of chlorophyll a on the value of the light flux by linear splines. The advantage of the proposed approach is a clear definition of the point of change of the limiting factor. It is shown that light-limited photosynthesis rate is determined not only by external irradiation, but also by the concentration of chlorophyll a. The light-saturated rate depends on the amount of a key enzyme complex, which limits the rate of energy exchange reactions in the cell. Verification of the proposed model on the example of the diatom microalgae Skeletonema costatum was carried out. It is shown that the higher the degree of cell adaptation to high irradiation, the better the photosynthesis curve is described by linear splines. If S. costatum cells are adapted to low irradiation, deviations of experimental data from the idealized broken line are observed, which are caused by changes in the pigment composition. When the experimental data are normalized, the cell adaptation factor is reduced, all points are described by a single broken line, which indicates the universality of the proposed approach.


2020 ◽  
Author(s):  
Elisabeth Hofmeister ◽  
Jisoo Woo ◽  
Tobias Ullrich ◽  
Lydia Petermann ◽  
Kevin Hanus ◽  
...  

Cobaloximes and their BF<sub>2</sub>-bridged analogues have emerged as promising non-noble metal catalysts for the photocatalytic hydrogen evolution reaction (HER). Herein we report the serendipitous discovery that double complex salts such as [Co(dmgh)<sub>2</sub>py<sub>2</sub>]<sup>+</sup>[Co(dmgBPh<sub>2</sub>)<sub>2</sub>Cl<sub>2</sub>]<sup>-</sup> can be obtained in good yields by treatment of commercially available [Co(dmgh)<sub>2</sub>pyCl] with triarylboranes. A systematic study on the use of such double complex salts and their single salts with simple counterions as photocatalysts revealed HER activities comparable or superior to existing cobaloxime catalysts and suggests ample opportunities for this compound class in catalyst/photosensitizer dyads and immobilized architectures. Preliminary electrochemical and spectroscopic studies indicate that one key advantage of these charged cobalt complexes is that the reduction potentials as well as the electrostatic interaction with charged photosensitizers can be tuned.


2020 ◽  
Author(s):  
Shogo Mori ◽  
Takahiro Aoki ◽  
Kaliyamoorthy Selvam ◽  
Shunichi Fukuzumi ◽  
Jieun Jung ◽  
...  

Despite the continuing popularity of radical reactions in organic synthesis, much remains to be explored in this area. Herein, we describe how spatiotemporal control can be exerted over the formation and reactivity of divergent exchangeable formamide radicals using nickel complexes with a semiconductor material (TiO<sub>2</sub>) under irradiation from near-UV–Vis light. Depending on the bipyridine ligand used and the quantity of the nickel complex that is hybridized on or nonhydridized over the TiO<sub>2</sub> surface, these radicals selectively undergo substitution reactions at the carbon center of carbon–bromine bonds that proceed via three different pathways. As the scalable production of formamides from CO<sub>2</sub> does not produce salt waste, these methods could add a new dimension to the search for carbon neutrality through the indirect incorporation of CO<sub>2</sub> into organic frameworks.


2019 ◽  
Author(s):  
Swaraj Sengupta ◽  
Sahanwaj Khan ◽  
Shyamal K. Chattopadhyay ◽  
Indrani Banerjee ◽  
Tarun K. Panda ◽  
...  

Synthesis and characterisation of one trinuclear copper complex, ([Cu<sub>3</sub>L<sub>3</sub>O]ClO<sub>4</sub>) (<b>1</b>) and one nickel complex ([Ni(L'H)<sub>2</sub>(dmso)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub>) (<b>2</b>) with Schiff base ligands: (3Z)-3-((Z)-(1-(thiophen-2-yl)ethylidene)hydrazono)butan-2-one oxime (LH) and 1-(pyridin-2-yl)ethylidene)hydrazono)butan-2-one oxime (L<sup>'</sup>H). <b>1</b> shows high catecholase activity and has also been tested as a catalyst for the synthesis of benzylimine. <b>2 </b> shows phenoxazinone synthase activity.


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