Polyfluoroalkyl derivatives of nitrogen. Part XXXIV. The kinetics of the gas-phase thermal decomposition of trifluoroacetyl nitrite. The slow reaction

1972 ◽  
pp. 773 ◽  
Author(s):  
R. Gibbs ◽  
R. N. Haszeldine ◽  
R. F. Simmons
Keyword(s):  
Thermal Decomposition ◽  
Gas Phase ◽  
Slow Reaction ◽  
Kinetics Of ◽  
Derivatives Of

The Elimination Reactions of Some Alkyl Cyanides in the Gas Phase

1973 ◽  
Vol 51 (3) ◽  
pp. 366-369 ◽  
Author(s):  
P. N. Dastoor ◽  
E. U. Emovon
Keyword(s):  
Thermal Decomposition ◽  
Gas Phase ◽  
Rate Constants ◽  
Flow System ◽  
Elimination Reactions ◽  
Kinetics Of

The kinetics of the thermal decomposition of ethyl, isopropyl, and t-butyl cyanides into HCN and the corresponding defines have been studied in a seasoned silica vessel in a flow system in the absence and presence of toluene as inhibitor. The reactions are homogeneous and the unimolecular rate constants are expressible by the following Arrhenius equations:[Formula: see text]

The Kinetics of the Homogeneous Gas Phase Thermal Decomposition of Ozone1

1960 ◽  
Vol 82 (11) ◽  
pp. 2682-2686 ◽  
Author(s):  
J. A. Zaslowsky ◽  
H. B. Urbach ◽  
F. Leighton ◽  
R. J. Wnuk ◽  
J. A. Wojtowicz
Keyword(s):  
Thermal Decomposition ◽  
Gas Phase ◽  
Kinetics Of
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