Kinetics of the thermal decomposition of alkyl derivatives of Group III and V elements

1995 ◽  
Vol 64 (10) ◽  
pp. 953-966 ◽  
Author(s):  
Veniamin A Yablokov ◽  
Nina V Yablokova
Keyword(s):  
Thermal Decomposition ◽  
Group Iii ◽  
Alkyl Derivatives ◽  
Kinetics Of ◽  
Derivatives Of

Reaction of carboranes with alkyl derivatives of group III metals

1988 ◽  
Vol 37 (3) ◽  
pp. 570-573
Author(s):  
V. I. Bregadze ◽  
A. Ya. Usyatinskii ◽  
V. A. Antonovich ◽  
N. N. Godovikov
Keyword(s):  
Group Iii ◽  
Alkyl Derivatives ◽  
Derivatives Of

Studies on metal hydroxy compounds. IX. Kinetics of thermal decomposition of twelve copper halide derivatives

1969 ◽  
Vol 47 (20) ◽  
pp. 3915-3918 ◽  
Author(s):  
P. Ramamurthy ◽  
E. A. Secco
Keyword(s):  
Thermal Decomposition ◽  
Copper Hydroxide ◽  
Copper Halide ◽  
Complex Theory ◽  
Kinetics Of Thermal Decomposition ◽  
Hydroxy Compounds ◽  
Kinetics Of ◽  
Derivatives Of ◽  
Activated Complex

The kinetics of the thermal decomposition of 12 halide (F, Cl, Br, I) derivatives of copper hydroxide are reported. The kinetic results and their interpretation in terms of activated complex theory are compared with the results and interpretation of the thermal decomposition of zinc and cadmium hydroxyhalides.

Reactions of ethyl 2-alkyl-3-oxobutanoate with thiourea and methylthiourea

1983 ◽  
Vol 48 (7) ◽  
pp. 1872-1877 ◽  
Author(s):  
Jaromír Kaválek ◽  
Vladimír Macháček ◽  
Vojeslav Štěrba
Keyword(s):  
Reaction Mechanism ◽  
Dissociation Constants ◽  
Reaction Rates ◽  
Medium Effects ◽  
Alkyl Derivatives ◽  
Alkyl Groups ◽  
Independent Synthesis ◽  
Kinetics Of ◽  
Derivatives Of

The reaction of ethyl 3-oxobutanoate with N-methylthiourea in alkoxide medium gives a mixture (1 : 20) of 1,6-dimethyl-2-thiouracil and 3,6-dimethyl-2-thiouracil: the latter isomer has been isolated from the mixture and the former isomer has been prepared by independent synthesis. Dissociation constants of ethyl 2-alkyl-3-oxobutanoates (alkyl = methyl, butyl, or isopropyl) have been measured in methanol. Reaction of these esters with thiourea and N-methylthiourea gives the corresponding alkyl derivatives of 6-methyl-2-thiouracil. Kinetics of these reactions have been measured in methoxide medium. Effects of the alkyl groups on the reaction rates have been investigated, and a reaction mechanism is suggested.

Reactions of sterically hindered o-quinones with alkyl derivatives of group III elements

1977 ◽  
Vol 26 (5) ◽  
pp. 1034-1037 ◽  
Author(s):  
G. A. Razuvaev ◽  
G. A. Abakumov ◽  
E. S. Klimov ◽  
E. N. Gladyshev ◽  
P. Ya. Bayushkin
Keyword(s):  
Group Iii ◽  
Alkyl Derivatives ◽  
Sterically Hindered ◽  
Derivatives Of
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