A kinetic study of the reaction of tert-butyl hydroperoxide with iron(III) 5, 10, 15, 20-tetra(4-sulfonatophenyl)porphyrin and related compounds in aqueous solution

1995 ◽  
pp. 235 ◽  
Author(s):  
Nicola Colclough ◽  
John R. Lindsay Smith
Keyword(s):  
Aqueous Solution ◽  
Kinetic Study ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Related Compounds

The radical versus ionic mechanisms of reduced cobalamin inactivation by tert-butyl hydroperoxide and hydrogen peroxide in aqueous solution

2021 ◽  
Author(s):  
Denis S. Salnikov ◽  
Sergei V. Makarov ◽  
Oscar I. Koifman
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Ionic Mechanisms

It was demonstrated that antioxidants cannot protect reduced cobalamin against its modification by hydrogen peroxide.

scholarly journals Mechanism of protection of adenosine from tert-butoxyl radicals and repair of adenosine radicals by α-tocopherol in aqueous solution

2014 ◽  
Vol 7 (1) ◽  
Author(s):  
G. Vijayalakshmmi ◽  
M. Adinarayanna ◽  
P. Jayaprrakash Rao
Keyword(s):  
Aqueous Solution ◽  
Rate Constant ◽  
Butyl Alcohol ◽  
Quantum Yields ◽  
Oh Radicals ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Tert Butyl Alcohol

The rates of oxidation of adenosine and α-tocopherol by tert-butoxyl radicals (t-BuO•) were studied spectrophotometrically. Radicals (t-BuO•) were generated by the photolysis of tert-butyl hydroperoxide (t-BuOOH) in presence of tert-butyl alcohol to scavenge •OH radicals. The rates and the quantum yields () of oxidation of α-tocopherol by t-BuO• radicals were determined in the absence and presence of varying concentrations of adenosine. An increase in the concentration of adenosine was found to decrease the rate of oxidation of α-tocopherol, suggesting that adenosine and α-tocopherol competed for t-BuO• radicals. From competition kinetics, the rate constant of α-tocopherol reaction with t-BuO• was calculated to be 7.29 x 108 dm3 mol-1 s-1. The quantum yields expt and cal values suggested that α-tocopherol not only protected adenosine from t-BuO• radicals, but also repaired adenosine radicals, formed by the reaction of adenosine with t-BuO• radicals.

scholarly journals Kinetic study and modeling of the Schotten-Baumann synthesis of peroxyesters using phase-transfer catalysts in a capillary microreactor

2021 ◽  
Author(s):  
Maurilio Magosso ◽  
Michel van den Berg ◽  
John van der Schaaf
Keyword(s):  
Kinetic Study ◽  
Phase Transfer ◽  
Strong Base ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Phase Transfer Catalysts ◽  
Capillary Microreactor ◽  
Tert Butyl Hydroperoxide ◽  
Kinetics Of

The kinetics of the synthesis of tert-butyl peroxy-2-ethylhexanoate were investigated in a capillary microreactor. TBPEH was synthesized from 2-ethylhexanoyl chloride and tert-butyl hydroperoxide in the presence of a strong base,...

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