The magnetic phase transition in layered cesium rare earth metal dimolybdates

1989 ◽  
Vol 50 (11) ◽  
pp. 1297-1299 ◽  
Author(s):  
P. Stefányi ◽  
A. Feher ◽  
A. Orendáčová ◽  
E.E. Anders ◽  
A.I. Zvyagin
Keyword(s):  
Phase Transition ◽  
Rare Earth ◽  
Magnetic Phase Transition ◽  
Rare Earth Metal ◽  
Magnetic Phase ◽  
Earth Metal

Magnetic phase transition in the metal-rich rare-earth carbide halidesGd2XC (X= Br,I)

1995 ◽  
Vol 52 (5) ◽  
pp. 3546-3554 ◽  
Author(s):  
R. Reisser ◽  
R. K. Kremer ◽  
A. Simon
Keyword(s):  
Phase Transition ◽  
Rare Earth ◽  
Magnetic Phase Transition ◽  
Magnetic Phase

Magnetic phase transition and magnetic properties in rare-earth-based RAl3C3 layered carbides

2021 ◽  
Vol 540 ◽  
pp. 168445
Author(s):  
Shuli Sun ◽  
Rui Liu ◽  
Guiquan Yao ◽  
Zhaohui Chen ◽  
Qiang Wang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Magnetic Properties ◽  
Rare Earth ◽  
Magnetic Phase Transition ◽  
Magnetic Phase

Peculiarities of Elastic Properties of RE Cobaltites RBaCo4O7 (R = Dy - Er, Y) at Magnetic Phase Transitions

2015 ◽  
Vol 233-234 ◽  
pp. 145-148 ◽  
Author(s):  
Zoya Kazei ◽  
Vyacheslav Snegirev ◽  
Alexander Andreenko ◽  
Ludmila Kozeeva ◽  
Margarita Kameneva
Keyword(s):  
Phase Transition ◽  
Rare Earth ◽  
Young’S Modulus ◽  
Magnetic Phase Transition ◽  
Magnetic Phase ◽  
Young's Modulus ◽  
Exchange Interactions ◽  
Magnetic Phase Transitions ◽  
Wide Range ◽  
Irreversible Effects

It has been found that the temperature dependences of the Young’s modulus for rare-earth cobaltites RBaCo4O7 (R = Dy - Er, Y) exhibit significant hysteresis and irreversible effects over a wide range (80–280) K between the structural and magnetic phase transition temperatures. At the magnetic phase transition temperature, there are weak and smoothed anomalies of the Young’s modulus, which correlate with the low dimensionality and frustration of the exchange interactions in the Kagome lattice of the Co subsystem for the studied rare-earth cobaltites.

Discotic liquid crystals of transition metal complexes 41: influence of rare-earth metal ions on clearing points of sandwich-type bis[octakis(3,4-didodecyloxyphenoxy)phthalocyaninato]lanthanoid(III) complexes

2009 ◽  
Vol 13 (08n09) ◽  
pp. 927-932 ◽  
Author(s):  
Hidetomo Mukai ◽  
Kazuaki Hatsusaka ◽  
Kazuchika Ohta
Keyword(s):  
Phase Transition ◽  
Rare Earth ◽  
Metal Ions ◽  
Metal Complexes ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Central Metal ◽  
Phase Transition Behavior ◽  
Transition Behavior ◽  
Sandwich Type

It has long been believed that the phase transition behavior and clearing points (c.p.s.) of phthalocyanine-based metallomesogens scarcely change regardless of the kind of central metal. In this work, we have synthesized a series of novel sandwich-type phthalocyanine-based lanthanoid complexes, bis[2,3,9,10,16,17,23,24-octakis(3,4-didodecyloxyphenoxy)phthalocyaninato]lanthanoid(III) (abbreviated as {[(C12O)2PhO]8Pc}2M, M = La, Ce, Eu, Gd, Tb, Yb and Lu : 1–7). Their mesomorphic properties were investigated by polarization microscope, DSC and temperature-dependent X-ray diffraction techniques to compare with the phase transition behavior and c.p.s. of the complexes. Very interestingly, the c.p.s. of these seven rare-earth metal complexes increased in an order of La (1) → Ce (2) → Eu (3), reached to a maximum for Gd (4), and decreased in an order of Tb (5) → Yb (6) → Lu (7). We have noticed that their rise and fall of c.p.s. correspond to the values of total spin quantum number (S) of the central rare-earth metal ions. Thus, it was found, for the first time in metallomesogens, that the S values of central rare-earth metal ions strongly influence their c.p.s.

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