scholarly journals Design and Development of Concretes for Special Rehabilitation Tasks

2018 ◽  
Vol 199 ◽  
pp. 07001
Author(s):  
Alexander Flohr ◽  
Andrea Osburg

The requirements for concrete restoration are not only aspects of retrofitting or restoration of bearing capacity but also aspects of preservation of historic structures, such as industrial monuments or civil engineering structures and buildings of the 1960s [1]. Thereby the facsimile replication of the concrete surface is a particular challenge. For the manufacture of delicate and complex structures with restricted accessibility self-compacting concrete (SCC) is well suited [2]. A modification with polymers normally ensures the durability of repair mortars or concretes (PCC) [3]. The combination of PCC and SCC to the Polymer-modified Self-Compacting Concrete (PSCC) for the restoration of historic concrete constructions is the logical consequence, to combine the advantages of both materials and is therefore an interesting alternative to well established materials and methods. Historic concrete constructions are often manufactured of concretes with very stiff consistencies, the so called tamped concretes. So there is a need to develop materials and methods for the rehabilitation of structures made of tamped concrete. For this reason, first investigations have been performed to the recipe development and optimization of its composition, but also properties, furthermore to the design possibilities and how polymers influence the concrete properties. In Germany between 1920 and 1970 industrial buildings and hydraulic structures have been built with concretes, where the content of Portland cement clinker was nearly complete substituted by latent hydraulic materials. The binders of those concretes contain large quantities of blast furnace slag and calcium sulphate and are called super-sulphated cement (SSC). Because of the high sulphate content, the compatibility of concrete structure with SSC is not given to concretes or mortars with other cements. If there is an adequate range of moisture, harmful new formations of phases will occur in the contact zone between SSC-concrete and the other concrete. In the field of rehabilitation PCC are well established. These are polymer-modified mortars or concretes with Portland cement, which are not suitable for the rehabilitation of structures of SSC-concrete. An alternative is the polymer-modification of SSC-concretes with polymers.

2021 ◽  
Vol 39 (4) ◽  
pp. 1001-1010
Author(s):  
A.D. Muhammad ◽  
Y.D. Amartey ◽  
J.M. Kaura ◽  
T.S. Ijimdiya ◽  
A. Lawan

The objective of this study was to investigate the suitability of Nigerian, sourced Gypsum for the manufacture of Portland cement. Gypsum samples were obtained from eighteen deposits across Nigeria. These were classified into five purity groups based on their calcium sulphate content.Foreign Gypsum, imported from Morocco, was used as control. Six cement samples where produced for each of the five Gypsum purity groups by grounding and blending cement clinker with 3%, 4%, 5%, 6% and 7% Gypsum content. The group 1 cement mix (having not more than 65% calcium sulphate content) has displayed flash set and could not be moulded and therefore not used for further analysis. Cement mortar prisms were produced for the groups 2, 3, 4 and 5 cement mixes, and subjected to flexural and compressive strength tests at 7, 14, 21 and 28 day curing periods. The cement mortar prisms were also subjected microstructure analysis at 7 and 28 days curing period. The spongy, gel and whitish colouration observed from the  microstructure of the specimens indicated silicates enriched regions which have proven the strength increase from 7 to 28 day curing period. The optimum gypsum content of 5.5% was recommended. The results show that all but the class one gypsum with less than 65% purity content are suitable for cement manufacture. Keywords: Gypsum, clinker, mortar, microstructure, compressive strength, flexural strength


Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5573
Author(s):  
Tim Schade ◽  
Bernhard Middendorf

This paper presents a model to calculate the sulphate agent amount and sulphate agent ratio for fine grounded and fast hardening Portland cement clinker. Despite sufficient knowledge about the influence of calcium sulphate on the hydration process of cement, the sulphate agent amount is mostly adjusted empirically. As a result, often a wide and unfeasible experimental matrix has to be tested. In this work, Design of Experiments (DoE) was used in combination with in-situ X-ray diffraction (XRD) tests to accurately adjust the sulphate agent of different finely ground cement by calculation. With only 42 tests, it was possible to analyse in total the influence of the sulphate agent, the grinding fineness and the use of C-S-H-seeds for the use in fast-hardening Portland cement-based systems. In addition, it was found that a hemihydrate to anhydrite content of 25/75 leads to a stabilisation of the hydrated system in the first 24 h of hydration. A model for the optimisation of the sulphate agent composition in dependency of the cement fineness could be determined. Furthermore, it was shown that the DoE also provides optimal results in material sciences in a resource-saving way.


Nature ◽  
1964 ◽  
Vol 203 (4941) ◽  
pp. 138-139 ◽  
Author(s):  
A. K. CHATTERJI ◽  
T. C. PHATAK

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1302
Author(s):  
Andrés Játiva ◽  
Evelyn Ruales ◽  
Miren Etxeberria

The construction industry is affected by the constant growth in the populations of urban areas. The demand for cement production has an increasing environmental impact, and there are urgent demands for alternative sustainable solutions. Volcanic ash (VA) is an abundant low-cost material that, because of its chemical composition and amorphous atomic structure, has been considered as a suitable material to replace Portland cement clinker for use as a binder in cement production. In the last decade, there has been interest in using alkali-activated VA material as an alternative material to replace ordinary Portland cement. In this way, a valuable product may be derived from a currently under-utilized material. Additionally, alkali-activated VA-based materials may be suitable for building applications because of their good densification behaviour, mechanical properties and low porosity. This article describes the most relevant findings from researchers around the world on the role of the chemical composition and mineral contents of VA on reactivity during the alkali-activation reaction; the effect of synthesis factors, which include the concentration of the alkaline activator, the solution-to-binder ratio and the curing conditions, on the properties of alkali-activated VA-based materials; and the mechanical performance and durability properties of these materials.


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