Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands

Synlett ◽  
2021 ◽  
Author(s):  
Ryotaro Niizeki ◽  
Kosuke Higashida ◽  
Emna Mejri ◽  
Masaya Sawamura ◽  
Yohei Shimizu
Keyword(s):  
Electronic Properties ◽  
Synthesis Method ◽  
Amide Ligands ◽  
Convenient Synthesis ◽  
Benzamide Derivatives ◽  
Three Component Coupling

A series of neutral C,N,N Au(III) complexes was synthesized with N-(8-quinolinyl)benzamide derivatives and chiral N-(2-(oxazolin-2-yl)phenyl)benzamide derivatives. This convenient synthesis method for amide ligands as well as an operationally simple complexation by direct C-H auration permitted changes to both the steric and electronic properties of the Au(III) complexes for promoting catalytic three-component coupling of an aldehyde, an amine, and an alkyne.

scholarly journals A convenient synthesis method for methylenomycin B and its application to methylenomycis A.

1981 ◽  
Vol 45 (1) ◽  
pp. 295-300 ◽  
Author(s):  
Kennosuke TONARI ◽  
Kozo MACHIYA ◽  
Itsuo ICHIMOTO ◽  
Hiroo UEDA
Keyword(s):  
Synthesis Method ◽  
Convenient Synthesis

A Convenient Synthesis Method for Methylenomycin B and Its Application to Methylenomycin A

1981 ◽  
Vol 45 (1) ◽  
pp. 295-300
Author(s):  
Kennosuke Tonari ◽  
Kôzo Machiya ◽  
Itsuo Ichimoto ◽  
Hiroo Ueda
Keyword(s):  
Synthesis Method ◽  
Convenient Synthesis

A convenient synthesis method of 5-oxopyrazolo[4,3-b]pyridine-6-carboxylic acids and their nitriles

2019 ◽  
Vol 55 (12) ◽  
pp. 1211-1216
Author(s):  
Georgiy G. Yakovenko ◽  
Oleh А. Lukianov ◽  
Andriy V. Bol’but ◽  
Mikhailo V. Vovk
Keyword(s):  
Carboxylic Acids ◽  
Synthesis Method ◽  
Convenient Synthesis

scholarly journals Connecting Experimental Synthetic Variables with the Microstructure and Electronic Properties of Doped Ferroelectric Oxides Using High-Throughput Frameworks

2020 ◽  
Author(s):  
Jose J Plata ◽  
Antonio Marquez ◽  
Santiago Cuesta-López ◽  
Javier Fdez. Sanz
Keyword(s):  
Solid Solution ◽  
Solar Cell ◽  
Dft Calculations ◽  
Electronic Properties ◽  
High Throughput ◽  
Synthesis Method ◽  
Systematic Exploration ◽  
Study Case ◽  
Ferroelectric Oxides ◽  
Microstructure Of The Material

<div> <div> <div> <p>Doping remains as the most used technique to photosensitize ferroelectric oxides for solar cell applications. However, optimizing these materials is still a challenge. First, many variables should be considered, for instance dopant nature and concentration, synthesis method or temperature. Second, all these variables should be connected with the microstructure of the solid solution and its optoelectronic properties. Here, a computational high-throughput framework that combines Boltzmann statistics with DFT calculations is presented as a solution to accelerate the optimization of theses materials for solar cells applications. This approach has two main advantages: i) the automatic and systematic exploration of the configurational space and ii) the connection between the changes in the microstructure of the material and its electronic properties. One of the most studied doped-ferroelectric systems, [KNbO3]1−x[BaNi1/2Nb1/2O3−δ]x, is used as a study case. Our results not only agree with previous theoretical and experimental reports, but also explain the effect of some of the variables to consider when this material is synthesized. </p> </div> </div> </div>

Short synthesis of polyfunctional sp3-rich threonine-derived morpholine scaffolds

2017 ◽  
Vol 15 (45) ◽  
pp. 9710-9717 ◽  
Author(s):  
Elena Lenci ◽  
Alessio Rossi ◽  
Gloria Menchi ◽  
Andrea Trabocchi
Keyword(s):  
Coupling Reaction ◽  
Convenient Synthesis ◽  
Short Synthesis ◽  
Three Component Coupling

A convenient synthesis of sp3-rich complex morpholines was achieved in two steps involving a Petasis three-component coupling reaction followed by an acid- or base-mediated cyclization.

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