Ammonium Tungstate as an Effective Catalyst for Selective Oxidation of Alcohols to Aldehydes or Ketones with Hydrogen Peroxide under Water – A Synergy of Graphene Oxide

Synlett ◽  
2017 ◽  
Vol 29 (04) ◽  
pp. 447-451 ◽  
Author(s):  
Xinhua Peng ◽  
Huihui Fu ◽  
Chuanfeng Hu ◽  
Zhida Huang ◽  
Jianhao Zhou
Keyword(s):  
Hydrogen Peroxide ◽  
Graphene Oxide ◽  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Efficient Catalyst ◽  
Effective Catalyst ◽  
Ammonium Tungstate ◽  
Water As Solvent ◽  
Oxidation Of Alcohols

Ammonium tungstate was found to be a facile and efficient catalyst for selective oxidation of alcohols to the corresponding carbonyl compounds with hydrogen peroxide as oxidant. Heterogeneous graphene oxide as acid effectively intensified the transformations and resulted in excellent yields. The use of water as solvent rendered the reactions promising both economically and environmentally.

Efficient and selective oxidation of alcohols to carbonyl compounds at room temperature by a ruthenium complex catalyst and hydrogen peroxide

2019 ◽  
Vol 43 (48) ◽  
pp. 19415-19421 ◽  
Author(s):  
Jie-Xiang Wang ◽  
Xian-Tai Zhou ◽  
Qi Han ◽  
Xiao-Xuan Guo ◽  
Xiao-Hui Liu ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Ruthenium Complex ◽  
Secondary Alcohols ◽  
Complex Catalyst ◽  
Efficient System ◽  
Oxidation Of Alcohols

An efficient system comprising a ruthenium complex and hydrogen peroxide was developed for the oxidation of various primary and secondary alcohols at room temperature.

ChemInform Abstract: Bis[2-(2-pyridyl)phenyl] Diselenide, a More Effective Catalyst for Oxidation of Alcohols to Carbonyl Compounds.

ChemInform ◽  
2010 ◽  
Vol 31 (33) ◽  
pp. no-no
Author(s):  
Hitoshi Ehara ◽  
Masato Noguchi ◽  
Shinsei Sayama ◽  
Tetsuo Onami
Keyword(s):  
Carbonyl Compounds ◽  
Effective Catalyst ◽  
Oxidation Of Alcohols

Membrane-Occluded Gold-Palladium Nanoclusters as Heterogeneous Catalysts for the Selective Oxidation of Alcohols to Carbonyl Compounds

2008 ◽  
Vol 350 (9) ◽  
pp. 1241-1247 ◽  
Author(s):  
P. G. N. Mertens ◽  
P. Vandezande ◽  
X. Ye ◽  
H. Poelman ◽  
D. E. De Vos ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Heterogeneous Catalysts ◽  
Oxidation Of Alcohols

scholarly journals Hydrogen Peroxide as a Green Oxidant for the Selective Catalytic Oxidation of Benzylic and Heterocyclic Alcohols in Different Media: An Overview

Chemistry ◽  
2020 ◽  
Vol 2 (1) ◽  
pp. 101-178
Author(s):  
Majid M. Heravi ◽  
Nastaran Ghalavand ◽  
Elaheh Hashemi
Keyword(s):  
Hydrogen Peroxide ◽  
Carbonyl Compounds ◽  
Aqueous Media ◽  
Environmental Concerns ◽  
Phase System ◽  
Dual Phase ◽  
Selective Catalytic Oxidation ◽  
Solvent Free Conditions ◽  
Oxidation Of Alcohols ◽  
Catalyzed Oxidation

Among a plethora of known and established oxidant in organic chemistry, hydrogen peroxide stands in a special position. It is commercially and inexpensively available, highly effective, selective, and more importantly it is compatible with current environmental concerns, dictated by principles of green chemistry. Several chemicals or their intermediates that are important in our daily life such as pharmaceuticals, flavors, fragrances, etc. are products of oxidation of alcohols. In this review, we introduce hydrogen peroxide as an effective, selective, green and privileged oxidant for the catalyzed oxidation of primary and secondary benzylic and heterocyclic alcohols to corresponding carbonyl compounds in different media such as aqueous media, under solvent-free conditions, various organic solvent, and dual-phase system.

Sign in / Sign up

Export Citation Format

Share Document