Stratospheric Ozone Depletion and Greenhouse Gases since the International Geophysical Year: F. Sherwood Rowland and the Evolution of Earth Science

2010 ◽  
pp. 355-371
Author(s):  
Dasan M. Thamattoor
2011 ◽  
Vol 24 (3) ◽  
pp. 795-812 ◽  
Author(s):  
Lorenzo M. Polvani ◽  
Darryn W. Waugh ◽  
Gustavo J. P. Correa ◽  
Seok-Woo Son

Abstract The importance of stratospheric ozone depletion on the atmospheric circulation of the troposphere is studied with an atmospheric general circulation model, the Community Atmospheric Model, version 3 (CAM3), for the second half of the twentieth century. In particular, the relative importance of ozone depletion is contrasted with that of increased greenhouse gases and accompanying sea surface temperature changes. By specifying ozone and greenhouse gas forcings independently, and performing long, time-slice integrations, it is shown that the impacts of ozone depletion are roughly 2–3 times larger than those associated with increased greenhouse gases, for the Southern Hemisphere tropospheric summer circulation. The formation of the ozone hole is shown to affect not only the polar tropopause and the latitudinal position of the midlatitude jet; it extends to the entire hemisphere, resulting in a broadening of the Hadley cell and a poleward extension of the subtropical dry zones. The CAM3 results are compared to and found to be in excellent agreement with those of the multimodel means of the recent Coupled Model Intercomparison Project (CMIP3) and Chemistry–Climate Model Validation (CCMVal2) simulations. This study, therefore, strongly suggests that most Southern Hemisphere tropospheric circulation changes, in austral summer over the second half of the twentieth century, have been caused by polar stratospheric ozone depletion.


1998 ◽  
Vol 16 (2) ◽  
pp. 67-75 ◽  
Author(s):  
Wen-Tien Tsai ◽  
Ching-Yuan Chang ◽  
Chih-Yin Ho

Of the major replacements for chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs) are now accepted as being prime contributors to stratospheric ozone depletion. As a consequence, the development of adsorbents capable of adsorbing and recovering specific HCFCs has received great attention. This paper describes an investigation of the adsorption equilibrium of 1, 1-dichloro-1-fluoroethane (HCFC-141b) vapour on a commercial hydrophobic zeolite. The corresponding Henry, Freundlich and Dubinin–Radushkevich (D–R) equilibrium isotherms have been determined and found to correlate well with the experimental data. Based on the Henry adsorption isotherms obtained at 283, 303 and 313 K. thermodynamic properties such as the enthalpy, free energy and entropy of adsorption have been computed for the adsorption of HCFC-141b vapour on the adsorbent. The results obtained could be useful in the application of HCFC adsorption on the hydrophobic zeolite studied.


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