Raman band shapes and dynamics of molecular motion for SF6in the supercritical dense fluid region

1981 ◽  
Vol 75 (4) ◽  
pp. 1612-1622 ◽  
Author(s):  
T. W. Żerda ◽  
J. Schroeder ◽  
J. Jonas
1990 ◽  
Vol 93 (7) ◽  
pp. 4659-4672 ◽  
Author(s):  
Masamichi Kobayashi ◽  
Hiroshi Koizumi ◽  
Yonhae Cho

1992 ◽  
Vol 89 ◽  
pp. 1755-1766 ◽  
Author(s):  
JH Williams ◽  
RP White

1974 ◽  
Vol 35 (C6) ◽  
pp. C6-131-C6-137 ◽  
Author(s):  
Y. HAZONY ◽  
R. H. HERBER

2019 ◽  
Vol 087 (04) ◽  
Author(s):  
Arthur Odom ◽  
Clare Bell
Keyword(s):  

2019 ◽  
Author(s):  
Haoke Zhang ◽  
Lili Du ◽  
Lin Wang ◽  
Junkai Liu ◽  
Qing Wan ◽  
...  

<p>Building molecular machine has long been a dream of scientists as it is expected to revolutionize many aspects of technology and medicine. Implementing the solid-state molecular motion is the prerequisite for a practical molecular machine. However, few works on solid-state molecular motion have been reported and it is almost impossible to “see” the motion even if it happens. Here the light-driven molecular motion in solid state is discovered in two non-conjugated molecules <i>s</i>-DPE and <i>s</i>-DPE-TM, resulting in the formation of excited-state though-space complex (ESTSC). Meanwhile, the newly formed ESTSC generates an abnormal visible emission which is termed as clusteroluminescence. Notably, the original packing structure can recover from ESTSC when the light source is removed. These processes have been confirmed by time-resolved spectroscopy and quantum mechanics calculation. This work provides a new strategy to manipulate and “see” solid-state molecular motion and gains new insights into the mechanistic picture of clusteroluminescence.<br></p>


2001 ◽  
Vol 15 (28n30) ◽  
pp. 3865-3868 ◽  
Author(s):  
H. MIYAOKA ◽  
T. KUZE ◽  
H. SANO ◽  
H. MORI ◽  
G. MIZUTANI ◽  
...  

We have obtained the Raman spectra of TiCl n (n= 2, 3, and 4). Assignments of the observed Raman bands were made by a normal mode analysis. The force constants were determined from the observed Raman band frequencies. We have found that the Ti-Cl stretching force constant increases as the oxidation number of the Ti species increases.


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