High resolution Fourier transform emission spectrum of the (2) 3Πg–A 3Πu transition of the B2 molecule

1994 ◽  
Vol 100 (11) ◽  
pp. 7928-7937 ◽  
Author(s):  
C. R. Brazier ◽  
Patrick G. Carrick
1994 ◽  
Vol 72 (11-12) ◽  
pp. 1213-1217 ◽  
Author(s):  
T. Karkanis ◽  
M. Dulick ◽  
Z. Morbi ◽  
J. B. White ◽  
P. F. Bernath

A high-resolution infrared emission spectrum of InF was recorded with a Fourier transform spectrometer. A total of 2664 rotational lines from ν = 1 → 0 to ν = 12 → 11 were measured for the major isotopomer 115InF and 179 lines for ν = 1 → 0 and ν = 2 → 1 for the minor isotope 113InF in the X1Σ+ ground state. Revised Dunham Yij constants for each isotopomer as well as isotopically invariant Dunham Uij constants are reported. Also, an effective Born–Oppenheimer potential was determined by fitting the data directly to the eigenvalues of a parameterized potential.


1990 ◽  
Vol 68 (11) ◽  
pp. 1257-1261 ◽  
Author(s):  
F. Roux ◽  
F. Michaud

Rotational analyses of vibrational levels of the B3Πg state, located above the dissociation threshold N(4S) + N(4S) were performed from a high-resolution emission spectrum recorded by Fourier transform spectrometry. Strong intensity perturbations were observed in the B3Πg vibrational levels ν′ = 13, 14, and 15.


1985 ◽  
Vol 50 (11) ◽  
pp. 2480-2492 ◽  
Author(s):  
Soňa Přádná ◽  
Dušan Papoušek ◽  
Jyrki Kauppinen ◽  
Sergei P. Belov ◽  
Andrei F. Krupnov ◽  
...  

Fourier transform spectra of the ν2 band of PH3 have been remeasured with 0.0045 cm-1 resolution. Ground state combination differences from these data have been fitted simultaneously with the microwave and submillimeterwave data to determine the ground state spectroscopical parameters of PH3 including the parameters of the Δk = ± 3n interactions. The correlation between the latter parameters has been discussed from the point of view of the existence of two equivalent effective rotational operators which are related by a unitary transformation. The ΔJ = 0, +1, ΔK = 0 (A1 ↔ A2, E ↔ E) rotational transitions in the ν2 and ν4 states have been measured for the first time by using a microwave spectrometer and a radiofrequency spectrometer with acoustic detection.


1978 ◽  
Vol 72 (2) ◽  
pp. 189-199 ◽  
Author(s):  
C Amiot ◽  
C Effantin ◽  
J d'Incan ◽  
J Verges

1976 ◽  
Vol 54 (24) ◽  
pp. 2429-2434 ◽  
Author(s):  
B. R. Yadav ◽  
S. B. Rai ◽  
D. K. Rai

The visible emission spectrum of the GdO molecule has been produced in a DC arc source and has been photographed in the first order of a 10.6 m grating spectrograph. Bands are shown to have a six-headed structure and improved vibrational constants have been obtained in this study. Isotopic shifts have been calculated for the various isotopic molecules. Tentative suggestions regarding the nature of the transition have been made.


2011 ◽  
Vol 134 (23) ◽  
pp. 234306 ◽  
Author(s):  
Michael K. Bane ◽  
Evan G. Robertson ◽  
Christopher D. Thompson ◽  
Chris Medcraft ◽  
Dominique R. T. Appadoo ◽  
...  

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