Direct observation of methyl rotor and vib-rotor states of S0 toluene: A revised torsional barrier due to torsion-vibration coupling

2015 ◽  
Vol 142 (2) ◽  
pp. 024315 ◽  
Author(s):  
Jason R. Gascooke ◽  
Edwina A. Virgo ◽  
Warren D. Lawrance
Keyword(s):  
Direct Observation ◽  
Torsional Barrier ◽  
Torsion Vibration ◽  
Vibration Coupling

Role of Torsion-Vibration Coupling in the Overtone Spectrum and Vibrationally Mediated Photochemistry of CH3OOH and HOOH

2017 ◽  
Vol 121 (48) ◽  
pp. 9262-9274 ◽  
Author(s):  
Laura C. Dzugan ◽  
Jamie Matthews ◽  
Amitabha Sinha ◽  
Anne B. McCoy
Keyword(s):  
Torsion Vibration ◽  
Vibration Coupling

Tracking molecular structure deformation of nitrobenzene and its torsion–vibration coupling by intense pumping CARS

2016 ◽  
Vol 25 (11) ◽  
pp. 114210
Author(s):  
Chang Wang ◽  
Hong-Lin Wu ◽  
Yun-Fei Song ◽  
Xing He ◽  
Yan-Qiang Yang ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Structure Deformation ◽  
Torsion Vibration ◽  
Vibration Coupling

scholarly journals Probing the origins of vibrational mode specificity in intramolecular dynamics through picosecond time-resolved photoelectron imaging studies

2017 ◽  
Vol 19 (7) ◽  
pp. 5051-5062 ◽  
Author(s):  
Julia A. Davies ◽  
Laura E. Whalley ◽  
Katharine L. Reid
Keyword(s):  
Energy Flow ◽  
Vibrational Mode ◽  
Imaging Studies ◽  
Intramolecular Dynamics ◽  
Photoelectron Imaging ◽  
Time Resolved ◽  
Torsion Vibration ◽  
Vibration Coupling ◽  
Intramolecular Energy Flow ◽  
Mode Specificity

Enhanced torsion-vibration coupling associated with a selected vibrational mode is shown to accelerate intramolecular energy flow in p-fluorotoluene.

State-to-State Time-of-Flight Measurements of NO Scattering from Au(111): Direct Observation of Translation-to-Vibration Coupling in Electronically Nonadiabatic Energy Transfer

2013 ◽  
Vol 117 (36) ◽  
pp. 8750-8760 ◽  
Author(s):  
Kai Golibrzuch ◽  
Pranav R. Shirhatti ◽  
Jan Altschäffel ◽  
Igor Rahinov ◽  
Daniel J. Auerbach ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Direct Observation ◽  
Time Of Flight ◽  
State Time ◽  
Vibration Coupling ◽  
Flight Measurements
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