scholarly journals Optimizing purity and recovery of hydrogen from syngas by equalized pressure swing adsorption using palm kernel shell activated carbon adsorbent

2019 ◽  
Author(s):  
I. Idris ◽  
A. Abdullah ◽  
I. K. Shamsudin ◽  
M. R. Othman
Author(s):  
Y. Yerima ◽  
I. Eiroboyi ◽  
I. Eiroboyi

Biomass-based activated carbon has received large attention due to its excellent characteristics such as inexpensiveness, good absorption behaviour, and potential to reduce strong dependence towards non-renewable precursors. The potential use of Palm Kernel Shell in modified activated carbon was evaluated by using the Response Surface Methodology. In this study, a 23 three-level Central Composite Design (CCD) was used to develop a statistical model for the optimization of process variables, contact time (10-130mins) X1, pH (5.0 – 8.0) X2, and adsorbent dose (0.4 -5.0g) X3. The investigation shows that Ethylene Di-Amine Tetra-Acetic Acid modified activated carbon prepared from Palm Kernel Shell is a promising adsorbent for the removal of copper ions from aqueous solutions over a wide range of concentrations with an optimized efficiency of 99% at the solution pH of 7.2, contact time of 70 minutes and adsorbent dose of 2.1g/L. The adsorption results are in line with the linear and quadratic model representation, which is evident from the models for optimization of copper ions.


2019 ◽  
Vol 6 (2) ◽  
pp. 106-112
Author(s):  
Hassan Rezaei ◽  
Saeedeh Rastegar ◽  
Sanaz Naseri

Developing an adsorbent with natural components is one of the effective methods to reduce the amount of wastewater pollutants. Wastewater reuse can improve the quality of water prior to entering the natural environment. The aim of this study was to evaluate the efficiency of chitosan nano-composite and activated carbon adsorbent in the removal of nitrite, phosphate, and ammonia pollutants from fish farms of Aq-Qala. To prepare the adsorbents, the shrimp shells were converted to nano-chitosan. The date palm kernel was prepared and activated with oxalic acid in pyrolysis furnace by injecting nitrogen gas into activated carbon, then, the nano-composite was prepared from nanochitosan and activated carbon. A field-laboratory study was conducted during the winter of 2018, and then, batches of synthesized nano-composite were investigated and the effects of pH, initial effluent concentration, and adsorption time were investigated. The experiments were performed in the pH range of 5-8, effluent concentration of 25-100 mg/L, and contact time of 15-90 minutes. The results showed that at optimum conditions (pH of 7, effluent concentration of 50 mg/L, and contact time of 60 minutes), the highest removal percentage and adsorption capacity for nitrite, phosphate, and ammonia contaminants were 99.98%, 99.77%, and 65.65%, and 6.65, 6.14, and 7.32 mg/g , respectively. Due to the high removal percentage (99.98%) of the chitosan and activated carbon nano-composite, the adsorbent was highly capable of removing pollutants (nitrite, phosphate, and ammonia).


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