scholarly journals Optimization of the Production of Ethylene Di-Amine Tetra-Acetic Acid Modified Activated Carbon using Palm Kernel Shell for the Adsorption of Copper ion

Author(s):  
Y. Yerima ◽  
I. Eiroboyi ◽  
I. Eiroboyi

Biomass-based activated carbon has received large attention due to its excellent characteristics such as inexpensiveness, good absorption behaviour, and potential to reduce strong dependence towards non-renewable precursors. The potential use of Palm Kernel Shell in modified activated carbon was evaluated by using the Response Surface Methodology. In this study, a 23 three-level Central Composite Design (CCD) was used to develop a statistical model for the optimization of process variables, contact time (10-130mins) X1, pH (5.0 – 8.0) X2, and adsorbent dose (0.4 -5.0g) X3. The investigation shows that Ethylene Di-Amine Tetra-Acetic Acid modified activated carbon prepared from Palm Kernel Shell is a promising adsorbent for the removal of copper ions from aqueous solutions over a wide range of concentrations with an optimized efficiency of 99% at the solution pH of 7.2, contact time of 70 minutes and adsorbent dose of 2.1g/L. The adsorption results are in line with the linear and quadratic model representation, which is evident from the models for optimization of copper ions.

Author(s):  
Y. Yerima ◽  
I. Eiroboyi ◽  
W. A. Raji ◽  
Y. I. Osakue

There is increasing research on the adsorption of lead because its use in industrial processes has resulted in various forms of environmental contamination and negative human health issues. Currently, researchers have intensified their search for low-cost adsorbents like activated carbon produced from nonfossil sources. This study is focused on the use of Ethylene Di-Amine Tetra-Acetic Acid for the adsorption of Lead ions. It was conducted to optimize the process variables in the production of Palm Kernel Shell Activated Carbon modified with Ethylene Di-Amine Tetra-Acetic Acid. A 23 three-level Central Composite Design was used to develop a statistical model for the optimization of the time (10-130) X1, pH (5.0 – 7.0) X2, and adsorbent dose (0.4 -5.0g)X3. Data obtained from RSM on activated carbon production were subjected to ANOVA and analyzed using a second-order polynomial equation. The extent of lead ion removal by Ethylene Di-Amine Tetra-Acetic Acid activated carbon from aqueous solution was 96.30% at the solution pH of 7.2, contact time of 70 minutes, and an adsorbent dose of 2.1g/L. The Langmuir isotherm model was in good agreement with the experimental data.


2014 ◽  
Vol 911 ◽  
pp. 326-330 ◽  
Author(s):  
Piaw Phatai ◽  
Jutharatana Klinkaewnarong ◽  
Surachai Yaiyen

The present work proposes the adsorption of methyl violet (MV) from two solution systems including single MV and binary MV-Cu2+systems by activated carbon (AC) prepared from tamarind seeds in a batch system. Parameters including contact time, solution pH, adsorbent dose, and initial dye concentration were studied. The morphology of the AC was determined by scanning electron microscopy (SEM). The results showed the maximum adsorption of MV dye onto the AC at a contact time of 60 min, solution pH of 9.0 and adsorbent dose of 0.2 and 0.5 g for the single and binary solution systems, respectively. The presence of copper ions in binary solution system decreased the adsorption efficiency of MV dye onto the AC. The equilibrium adsorption data were analyzed using Langmuir, Freundlich and Temkin isotherms.


2019 ◽  
Vol 6 (2) ◽  
pp. 106-112
Author(s):  
Hassan Rezaei ◽  
Saeedeh Rastegar ◽  
Sanaz Naseri

Developing an adsorbent with natural components is one of the effective methods to reduce the amount of wastewater pollutants. Wastewater reuse can improve the quality of water prior to entering the natural environment. The aim of this study was to evaluate the efficiency of chitosan nano-composite and activated carbon adsorbent in the removal of nitrite, phosphate, and ammonia pollutants from fish farms of Aq-Qala. To prepare the adsorbents, the shrimp shells were converted to nano-chitosan. The date palm kernel was prepared and activated with oxalic acid in pyrolysis furnace by injecting nitrogen gas into activated carbon, then, the nano-composite was prepared from nanochitosan and activated carbon. A field-laboratory study was conducted during the winter of 2018, and then, batches of synthesized nano-composite were investigated and the effects of pH, initial effluent concentration, and adsorption time were investigated. The experiments were performed in the pH range of 5-8, effluent concentration of 25-100 mg/L, and contact time of 15-90 minutes. The results showed that at optimum conditions (pH of 7, effluent concentration of 50 mg/L, and contact time of 60 minutes), the highest removal percentage and adsorption capacity for nitrite, phosphate, and ammonia contaminants were 99.98%, 99.77%, and 65.65%, and 6.65, 6.14, and 7.32 mg/g , respectively. Due to the high removal percentage (99.98%) of the chitosan and activated carbon nano-composite, the adsorbent was highly capable of removing pollutants (nitrite, phosphate, and ammonia).


Sign in / Sign up

Export Citation Format

Share Document