scholarly journals Exact generator and its high order expansions in time-convolutionless generalized master equation: Applications to spin-boson model and excitation energy transfer

2018 ◽  
Vol 31 (4) ◽  
pp. 575-583
Author(s):  
Yan-ying Liu ◽  
Ya-ming Yan ◽  
Meng Xu ◽  
Kai Song ◽  
Qiang Shi
1987 ◽  
Vol 42 (8) ◽  
pp. 813-818
Author(s):  
A. Kawski ◽  
J. Kamiński

A theory of the excitation energy transfer between like molecules in isotropic solution based on a centre or shell model of a primarily excited luminescent molecule and on the extended Förster “excitation master equation” has been elaborated. Fluorescence and phosphorescence depolarization are shown to be governed by singlet-singlet energy migration and described by the same expression. The comparison of the theoretical curve with the experimental data obtained by Gondo et al. (1975) for benzo[f]quinoline in ethanol glass at 77 K results in the following critical distance R0 for the excitation energy migration: 21.5 Å for fluorescence and phosphorescence, respectively.


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