Probing the Size-Dependent Polarizability of Mesoscopic Ionic Clusters and Their Induced-Dipole Interactions

2021 ◽  
Author(s):  
Trung Dac Nguyen ◽  
Felipe Jimenez-Angeles ◽  
Monica Olvera de la Cruz
Keyword(s):  
Ionic Clusters ◽  
Size Dependent ◽  
Dipole Interactions ◽  
Induced Dipole

scholarly journals Theoretical Prediction on the New Types of Noble Gas Containing Anions OBONgO− and OCNNgO− (Ng=He, Ar, Kr and Xe)

Molecules ◽  
2020 ◽  
Vol 25 (24) ◽  
pp. 5839
Author(s):  
Cheng-Cheng Tsai ◽  
Yu-Wei Lu ◽  
Wei-Ping Hu
Keyword(s):  
Density Functional Theory ◽  
Electron Density Distribution ◽  
Density Functional ◽  
Noble Gas ◽  
Structure Calculation ◽  
Molecular Structures ◽  
Fluoride Ion ◽  
Functional Theory ◽  
Dipole Interactions ◽  
Induced Dipole

The fluorine-less noble gas containing anions OBONgO− and OCNNgO− have been studied by correlated electronic structure calculation and density functional theory. The obtained energetics indicates that for Ng=Kr and Xe, these anions should be kinetically stable at low temperature. The molecular structures and electron density distribution suggests that these anions are stabilized by ion-induced dipole interactions with charges concentrated on the electronegative OBO and OCN groups. The current study shows that in addition to the fluoride ion, polyatomic groups with strong electronic affinities can also form stable noble gas containing anions of the type Y−…NgO.

THE CRYSTAL SPECTRUM OF PERYLENE

1961 ◽  
Vol 39 (3) ◽  
pp. 451-458 ◽  
Author(s):  
Robin M. Hochstrasser
Keyword(s):  
Absorption Spectrum ◽  
Electronic Absorption ◽  
Weak Coupling ◽  
Room Temperature ◽  
Excited Level ◽  
Vibrational Structure ◽  
Factor Group ◽  
Electronic Band ◽  
Dipole Interactions ◽  
Induced Dipole

The electronic absorption spectrum of crystalline perylene has been examined in the spectral region 3000–4700 Å. The lowest energy electronic state of perylene has a large oscillator strength and the crystal spectrum deviates considerably from that calculated from a weak coupling (Davydov) model.The sublimation flakes were examined at room temperature and at the temperature of boiling nitrogen. The lowest energy crystal state was polarized along the crystallographic a-axis (Bu) and the factor group splitting of lowest vibrational envelope of the electronic band was 800 cm−1. The whole spectrum was more intense along the a- than along the b-axis of the crystal. These results are consistent with the notion that the crystal spectrum is derived from dipole-induced dipole interactions between molecular B2u levels of perylene and neighboring unexcited molecules. This assignment of the lowest excited level of perylene is in agreement with theory.The molecular vibrational structure is severely altered in the crystal and the observed crystal shift is much smaller than that predicted by the Davydov theory.

scholarly journals Bimolecular Reactions of Trapped Ions. VI. Ion–Molecule Reactions Involving CH5+ and C2H5+

1973 ◽  
Vol 51 (10) ◽  
pp. 1645-1654 ◽  
Author(s):  
A. S. Blair ◽  
A. G. Harrison
Keyword(s):  
Proton Transfer ◽  
Trapped Ions ◽  
Rate Coefficients ◽  
Polar Molecules ◽  
Large Role ◽  
Bimolecular Reactions ◽  
Trapped Ion ◽  
Ion Molecule Reactions ◽  
Dipole Interactions ◽  
Induced Dipole

The ion–molecule reactions in mixtures of methane with the polar molecules dimethyl-d6 ether, ethylene-d4 oxide, acetaldehyde-d4, acetone, and acetonitrile have been studied using the trapped-ion technique. The CH5+ and C2H5+ ions produced by ion–molecule reactions in methane react rapidly (predominantly by proton transfer) with the polar molecules; the rate coefficients range from 1.98 × 10−9 cm3 molecule−1 s−1 (C2H5+ + C2D4O) to 5.26 × 10−9 cm3 molecule−1 s−1 (CH5+ + (CH3)2CO). The rate coefficients are much larger than those predicted from ion – induced dipole interactions only indicating that ion–dipole interactions play a large role in the collision process.Rate coefficients for reaction of CH3+ and CH4+ with the polar molecules also have been measured. Most of these also are larger than predicted from ion – induced dipole interactions indicating in this case as well substantial effects due to ion–dipole interactions.

Ion–molecule reactions in formic-d acid and methyl formate

1968 ◽  
Vol 46 (12) ◽  
pp. 2141-2146 ◽  
Author(s):  
Howard Pritchard ◽  
J. C. J. Thynne ◽  
A. G. Harrison
Keyword(s):  
Rate Constants ◽  
Methyl Formate ◽  
Ion Molecule Reactions ◽  
Dipole Interactions ◽  
Induced Dipole ◽  
Energy Formula ◽  
Good Agreement

The following ion–molecules reactions have been found to occur in DCOOH for ions produced by bombardment with electrons of 10–15 eV energy (all rate constants in cm3 molecule−1 units).[Formula: see text]In methyl formate the following reactions have been identified and rate constants measured for ions formed by bombardment with electrons of 10–15 eV energy.[Formula: see text]Experiments using DCO2CH3 show that reaction [f] involves transfer of the methyl hydrogen at a rate 1.5 times that of the formyl hydrogen while reaction [g] involves transfer from only the methyl position of CH3OH+. The rate constants for all reactions are considerably higher than predicted on the basis of ion–induced dipole interactions only but are in good agreement with values calculated by including ion–dipole interactions.

Precision Assembly of Oppositely and Like-Charged Nanoobjects Mediated by Charge-Induced Dipole Interactions

Nano Letters ◽  
2010 ◽  
Vol 10 (6) ◽  
pp. 2275-2280 ◽  
Author(s):  
David A. Walker ◽  
Christopher E. Wilmer ◽  
Bartlomiej Kowalczyk ◽  
Kyle J. M. Bishop ◽  
Bartosz A. Grzybowski
Keyword(s):  
Dipole Interactions ◽  
Induced Dipole

BOSE–EINSTEIN CONDENSATES WITH LASER-INDUCED DIPOLE–DIPOLE INTERACTIONS BEYOND THE MEAN-FIELD APPROACH

2004 ◽  
Vol 18 (07) ◽  
pp. 961-974 ◽  
Author(s):  
G. KURIZKI ◽  
I. E. MAZETS ◽  
D. H. J. O'DELL ◽  
W. P. SCHLEICH
Keyword(s):  
Mean Field ◽  
Field Approach ◽  
Field Effects ◽  
Dipole Interactions ◽  
Induced Dipole ◽  
The Mean ◽  
Dynamical Properties ◽  
Bose Einstein

We present a brief review of our recent results concerning non-mean-field effects of laser-induced dipole–dipole interactions on static and dynamical properties of atomic Bose–Einstein condensates.

scholarly journals Ion-Induced Dipole Interactions and Fragmentation Times: Cα-Cβ Chromophore Bond Dissociation Channel

2015 ◽  
Vol 6 (11) ◽  
pp. 2070-2074 ◽  
Author(s):  
Satchin Soorkia ◽  
Christophe Dehon ◽  
Sunil Kumar S ◽  
Marie Pérot-Taillandier ◽  
Bruno Lucas ◽  
...  
Keyword(s):  
Dissociation Channel ◽  
Bond Dissociation ◽  
Dipole Interactions ◽  
Induced Dipole
Sign in / Sign up

Export Citation Format

Share Document