Synthesis and Crystal Structure of [(CH2)6N4CH3]2[CoCl4]
Keyword(s):
The interesting three-dimensional hydrogen-bonded self-assembled network of [(CH2)6N4CH3]+ cations and [CoCl4]2– anions has been prepared and structurally characterized. In the title complex, the quaternization of one hexamethylenetetramine nitrogen atom has been trapped, and further stabilized by the large [CoCl4]2– anions, featuring C–H���Cl hydrogen bonds (3.497–3.709 �) between the methylene groups of [(CH2)6N4CH3]+ cations and the chlorine atoms of the [CoCl4]2– anions.
1992 ◽
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2013 ◽
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pp. m28-m29
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2006 ◽
Vol 62
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2019 ◽
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pp. 1001-1004
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Vol 72
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