Moulting hormones of insects and crustaceans: The synthesis of 22-deoxycrustecdysone
Keyword(s):
A partial synthesis of the title compound (III) has been accomplished from crustecdysone (I). Chromic acid oxidation of crustecdysone afforded the ketone (VI) which was converted into the corresponding acetonide silyl ether (IX). Alkylation of (IX) with the Grignard reagent from (XI) and hydrolysis of the protecting groups afforded the required compound (III). An alternative route which facilitates tritium labelling afforded the same product. The biological activity and spectral properties of the product are discussed.
1965 ◽
Vol 43
(12)
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pp. 3311-3321
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2015 ◽
Vol 52
(6)
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pp. 502-511
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1970 ◽
Vol 43
(3)
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pp. 590-594
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Keyword(s):
1952 ◽
Vol 74
(17)
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pp. 4387-4391
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Keyword(s):
2007 ◽
Vol 266
(1-2)
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pp. 21-30
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Keyword(s):
A Tracer Study on the Source of Carbon Dioxide in the Chromic Acid Oxidation of Toluene and Fluorene
1964 ◽
Vol 37
(9)
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pp. 1384-1385