Solvent structure. III. The dependence of partial molal volumes on internal pressure and solvent compressibility
Keyword(s):
Partial molal volumes, V�, at 25�C were measured for sucrose, ascorbic acid and aspirin in the solvents water, formamide, N,N-dimethylformamide and methanol. The dependence of V� on solvent compressibility enabled an estimate to be made of the intrinsic volumes, Vint, of the dissolved non-electrolytes. Effective pressures, Pe, in aqueous electrolyte solutions were calculated from previously determined internal pressure data. Substitution of Pe into the Tait-Gibson equation yielded values of Ve, the volume contraction of water due to electrostriction, which agree well with values obtained by other methods.
1972 ◽
Vol 76
(9)
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pp. 1333-1338
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1966 ◽
Vol 70
(7)
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pp. 2413-2416
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1972 ◽
Vol 77
(1-6)
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pp. 305-316
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1983 ◽
Vol 79
(5)
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pp. 1109
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1988 ◽
Vol 17
(5)
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pp. 399-415
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1972 ◽
Vol 76
(21)
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pp. 3044-3049
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1966 ◽
Vol 11
(8)
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pp. 987-996
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1981 ◽
Vol 22
(1)
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pp. 140-142
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