Quasi-biennial and quasi-triennial oscillations in the growth rates of atmospheric chlorofluorocarbons 11 and 12

The 12-monthly running means of CFC-11 and CFC-12 were examined for 1977-1992. As observed by earlier workers, during 1977-1988, there was a rapid, almost linear increase of these compounds, ~70% in the northern and ~77% in the southern hemisphere. From 1988 up to 1992, growth rates were slower, more so for CFC-11 in the northern hemisphere. Superposed on this pattern were QBO, QTO (Quasi-Biennial and Quasi-Triennial Oscillations). A spectral analysis of the various series indicated the following. The 50 hPa low latitude zonal wind had one prominent QBO peak at 2.58 years and much smaller peaks at 2.00 (QBO) and 5.1 years. The Southern oscillation index represented by (T-D), Tahiti minus Darwin atmospheric pressure, had a prominent peak at 4.1 years and a smaller peak at 2.31 years. CFC-11 had only one significant peak at 3.7 years in the southern hemisphere, roughly similar to the 4.1 year (T-D) peak. CFC-12 had prominent QBO (2.16-2.33 years) in both the hemispheres and a QTO (3.6 years) in the southern hemisphere. For individual locations, CFC-11 showed barely significant QBO in the range (1.95-3.07 years), while CFC 12 showed strong QBO in the range (1.86-2.38 years). The difference in the spectral characteristics of CFC-11 and CFC 12 time series is attributed to differences in their lifetimes (44 and 180 years), source emission rates and transport processes.

STRENGTHENING SPATIAL PERSPECTIVE THROUGH GIS APPLICATIONS IN TRANSPORT MODELING

The process of transporting passengers and goods takes place in space; therefore, geospatial foundations are considered in transport models. Considering conceptual, methodological and technical developments in this direction, the relevance of an integrated approach becomes obvi-ous. The article deals with geographic information systems and their application in modeling transport processes. Three areas are identified in which the spatial perspective contributes to effective modeling and increasing the reliability of the results obtained. The purpose of the study is to prove the prospects of spatial transport modeling with the integration of geographic information systems

Measuring anion binding at biomembrane interfaces

Understanding non-covalent molecular recognition events at biomembrane interfaces is important in biological, medicinal, and materials chemistry research.1 Despite the crucial regulatory roles of anion binding/transport processes at biomembranes, no information is available regarding how strongly anions can bind to naturally occurring or synthetic receptors in lipid bilayer environments compared to their well-established behaviour in solutions.2 To bridge this knowledge gap, we synthesised a flat macrocycle that possesses a record aqueous SO42– affinity among neutral receptors and exploited its unique fluorescence response at interfaces. We show that the determinants of anion binding are extraordinarily different in organic solvents and in lipid bilayers. The high charge density of dihydrogen phosphate and chloride ions prevails in DMSO, however in lipids they fail to bind the macrocycle. Perchlorate and iodide hardly bind in DMSO but show significant affinities for the macrocycle in lipids. Our results demonstrate a surprisingly great advantage of large, charge-diffuse anions to bind to a lipid-embedded synthetic receptor mainly attributed to their higher polarisabilities and deeper penetration into the bilayer, beyond the common knowledge of dehydration energy-governed selectivity. The elucidation of these principles enhances our understanding of biological anion recognition functions in membranes and guides the design of ionophores and molecular machines operating at biomembrane interfaces.

Reciprocity of thermal diffusion in time-modulated systems

The reciprocity principle governs the symmetry in transmission of electromagnetic and acoustic waves, as well as the diffusion of heat between two points in space, with important consequences for thermal management and energy harvesting. There has been significant recent interest in materials with time-modulated properties, which have been shown to efficiently break reciprocity for light, sound, and even charge diffusion. However, time modulation may not be a plausible approach to break thermal reciprocity, in contrast to the usual perception. We establish a theoretical framework to accurately describe the behavior of diffusive processes under time modulation, and prove that thermal reciprocity in dynamic materials is generally preserved by the continuity equation, unless some external bias or special material is considered. We then experimentally demonstrate reciprocal heat transfer in a time-modulated device. Our findings correct previous misconceptions regarding reciprocity breaking for thermal diffusion, revealing the generality of symmetry constraints in heat transfer, and clarifying its differences from other transport processes in what concerns the principles of reciprocity and microscopic reversibility.

Biotite supports long-range diffusive transport in dissolution–precipitation creep in halite through small porosity fluctuations

Phyllosilicates are generally regarded to have a reinforcing effect on chemical compaction by dissolution–precipitation creep (DPC) and thereby influence the evolution of hydraulic rock properties relevant to groundwater resources and geological repositories as well as fossil fuel reservoirs. We conducted oedometric compaction experiments on layered NaCl–biotite samples to test this assumption. In particular, we aim to analyse slow chemical compaction processes in the presence of biotite on the grain scale and determine the effects of chemical and mechanical feedbacks. We used time-resolved (4-D) microtomographic data to capture the dynamic evolution of the porosity in layered NaCl–NaCl/biotite samples over 1619 and 1932 h of compaction. Percolation analysis in combination with advanced digital volume correlation techniques showed that biotite grains influence the dynamic evolution of porosity in the sample by promoting a reduction of porosity in their vicinity. However, the lack of preferential strain localisation around phyllosilicates and a homogeneous distribution of axial shortening across the sample suggests that the porosity reduction is not achieved by pore collapse but by the precipitation of NaCl sourced from outside the NaCl–biotite layer. Our observations invite a renewed discussion of the effect of phyllosilicates on DPC, with a particular emphasis on the length scales of the processes involved. We propose that, in our experiments, the diffusive transport processes invoked in classical theoretical models of DPC are complemented by chemo-mechanical feedbacks that arise on longer length scales. These feedbacks drive NaCl diffusion from the marginal pure NaCl layers into the central NaCl–biotite mixture over distances of several hundred micrometres and several grain diameters. Such a mechanism was first postulated by Merino et al. (1983).

The system "seaport - "dry" port"

The monograph presents an approach to solving the problem of increasing the throughput and processing capacity of seaports in conditions of limiting their territorial dislocation and increasing the unevenness of external and internal cargo flows. The basis of the approach is the proposed system of the main parameters of the dry port and the methodology of simulation modeling of the functioning of the system "seaport - dry port". The material is illustrated with examples of the implementation of the developed approach, including model scenarios of multi-agent optimization of the parameters of the system under study. The proposed approach and the developed methodology can be used to justify management decisions on the balanced development of transport and logistics infrastructure of the regions hosting sea and dry ports. It is intended for specialists of transport and logistics companies, engineering and technical workers engaged in solving problems in the field of logistics, supply chain management and transport infrastructure design. In addition, it is recommended to students in the following programs: postgraduate studies 23.06.01 "Land transport engineering and technology" (focus "Transport and transport-technological systems of the country, its regions and cities, organization of production in transport") and 27.06.01 "Management in technical systems" (focus "Management of transportation processes"); master's degree 23.04.01 "Technology of transport processes" (profile "Organization of transportation and management in a single transport system"); bachelor's degree 38.03.02 "Management" (profile "Logistics") and 23.03.01 "Technology of transport processes".