The Raman spectra of Bis(hexamethylenetetramine)-iodine(I) and -bromine(I) perchlorates

The low-wavenumber (<200 cm-1) Raman spectra of bis(hexamethylenetetramine)iodine(I) perchlorate and bis(hexamethylenetetramine)bromine(I) perchlorate have been measured, and the nitrogen-halogen symmetric stretching mode of the cation has been assigned for each compound. The nitrogen-halogen bond stretching and interaction force constants for the cations have been calculated, and these are found to be very similar to those for the corresponding bis(pyridine)halogen(I) cations.

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Vibrational spectra of aquadioxotetra; peroxodivanadates(V) M2[V2O2(O2)4(H2O)]·xH2O (M = N(CH3)4, Cs)

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19901485 ◽

1990 ◽

Vol 55 (6) ◽

pp. 1485-1490 ◽

Cited By ~ 4

Author(s):

Peter Schwendt ◽

Milan Sýkora

Keyword(s):

Raman Spectra ◽

Vibrational Spectra ◽

Normal Coordinate Analysis ◽

Force Constants ◽

Infrared And Raman Spectra ◽

Empirical Correlations ◽

Normal Coordinate ◽

Bond Lengths ◽

Stretching Vibrations

The infrared and Raman spectra of M2[V2O2(O2)4(H2O)]·xH2O and M2[V2O2(O2)4(D2O)]·xD2O (M = N(CH3)4, Cs) were measured. In the region of the vanadium-oxygen stretching vibrations, the spectra were interpreted based on normal coordinate analysis, employing empirical correlations between the bond lengths and force constants.

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RAMAN SPECTRA OF TITANIUM DI-, TRI-, AND TETRA-CHLORIDES

International Journal of Modern Physics B ◽

10.1142/s021797920100886x ◽

2001 ◽

Vol 15 (28n30) ◽

pp. 3865-3868 ◽

Cited By ~ 2

Author(s):

H. MIYAOKA ◽

T. KUZE ◽

H. SANO ◽

H. MORI ◽

G. MIZUTANI ◽

...

Keyword(s):

Force Constant ◽

Raman Spectra ◽

Normal Mode ◽

Raman Band ◽

Normal Mode Analysis ◽

Force Constants ◽

Mode Analysis ◽

Oxidation Number

We have obtained the Raman spectra of TiCl n (n= 2, 3, and 4). Assignments of the observed Raman bands were made by a normal mode analysis. The force constants were determined from the observed Raman band frequencies. We have found that the Ti-Cl stretching force constant increases as the oxidation number of the Ti species increases.

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Schwingungsspektren und Kraftkonstanten der Hexacyano-Komplexe des Mangan(I), Technetium(I) und Rhenium(I) / Vibrational Spectra and Force Constants of the Hexacyano Complexes of Mangan(l), Technicium(I) and Rhenium(l)

Zeitschrift für Naturforschung A ◽

10.1515/zna-1972-8-905 ◽

1972 ◽

Vol 27 (8-9) ◽

pp. 1193-1196 ◽

Cited By ~ 8

Author(s):

W. Krasser ◽

K. Schwochau

Keyword(s):

Force Field ◽

Raman Spectra ◽

Vibrational Spectra ◽

Point Group ◽

Force Constants ◽

Irreducible Representations ◽

Infrared And Raman Spectra ◽

Valence Force ◽

Valence Force Field ◽

Complex Salts

The infrared and Raman spectra of the complex salts K5[Mn(CN)6], K5[Tc(CN)6] and K5[Re(CN)s] have been recorded in the range from 4000 to 40 cm-1. All expected fundamental vibrations have been observed and could be assigned to the irreducible representations of the symmetry point group Oh . The calculation of the force constants is based on the concept of the generalized valence force field. The low CN-valence force constants indicate the relatively strong Π-bonding character of the metal carbon bond, which is especially pronounced for K5[Tc(CN)6).

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Unlike pair potential interaction force constants for hydrogen-light hydrocarbon systems

AIChE Journal ◽

10.1002/aic.690210126 ◽

1975 ◽

Vol 21 (1) ◽

pp. 173-175 ◽

Cited By ~ 1

Author(s):

T.-C. Chu ◽

Patsy S. Chappelear ◽

Riki Kobayashi

Keyword(s):

Pair Potential ◽

Interaction Force ◽

Potential Interaction ◽

Light Hydrocarbon ◽

Force Constants

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Bond stretching force constants and compressibilities of nitride, oxide, and sulfide coordination polyhedra in molecules and crystals

Structural Chemistry ◽

10.1007/bf02252892 ◽

1994 ◽

Vol 5 (6) ◽

pp. 349-355 ◽

Cited By ~ 13

Author(s):

F. C. Hill ◽

G. V. Gibbs ◽

Monte B. Boisen

Keyword(s):

Force Constants ◽

Coordination Polyhedra ◽

Bond Stretching ◽

Nitride Oxide

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Raman spectra and force constants for Cl3+(SbF6)−

Spectrochimica Acta Part A Molecular Spectroscopy ◽

10.1016/0584-8539(91)80004-3 ◽

1991 ◽

Vol 47 (12) ◽

pp. 1673-1676 ◽

Cited By ~ 3

Author(s):

R. Minkwitz ◽

J. Nowicki ◽

H. Härtner ◽

W. Sawodny

Keyword(s):

Raman Spectra ◽

Force Constants

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Determination of interaction force constants for n‐alkanes using molecular beam techniques

The Journal of Chemical Physics ◽

10.1063/1.432479 ◽

1976 ◽

Vol 64 (5) ◽

pp. 2027-2038

Author(s):

T. W. Schmidt ◽

J. P. Guillory

Keyword(s):

Molecular Beam ◽

Interaction Force ◽

Force Constants

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The Vibrational Spectrum and Urey-Bradley Force Constants of the Trifluoromethyltrifluoroborate(1-) Anion

Applied Spectroscopy ◽

10.1366/000370273774333678 ◽

1973 ◽

Vol 27 (3) ◽

pp. 209-213 ◽

Cited By ~ 3

Author(s):

John F. Jackovitz ◽

Charles E. Falletta ◽

James C. Carter

Keyword(s):

Potential Energy ◽

Vibrational Spectrum ◽

Energy Distribution ◽

Force Field ◽

Raman Spectra ◽

Normal Modes ◽

Force Constants ◽

Potential Energy Distribution ◽

Infrared And Raman Spectra ◽

Normal Coordinate

Infrared and Raman spectra for (K+) (CF3BF3−) have been obtained from 4000 to 50 cm−1. Spectral assignments were made on the basis of C3v symmetry using both 10B and 11B compounds. In addition, a normal coordinate analysis was performed to obtain the potential energy distribution of the normal modes. A Urey-Bradley type force field was used, and force constants obtained for the CF3 and BF3 groupings were compared to those in C2F6 and BF4−.

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