Causes for the reduced reactivity of phosphate rock residues in partially acidulated phosphate rocks

Soil Research ◽  
1994 ◽  
Vol 32 (1) ◽  
pp. 95 ◽  
Author(s):  
HJ Di ◽  
LM Condron ◽  
AS Campbell ◽  
KM Goh ◽  
IS Cornforth
Keyword(s):  
North Carolina ◽  
Phosphate Rock ◽  
Water Soluble ◽  
Partially Acidulated Phosphate Rock ◽  
Ammonium Citrate ◽  
Insoluble Residue ◽  
Partial Acidulation ◽  
C:P Ratio ◽  
Fluoride Complexes ◽  
Acid Solubility

The agronomic effectiveness of partially acidulated phosphate rock (PAPR) fertilizers depends on the proportion of water soluble P present and the long-term release of P from the unacidulated residual phosphate rock (water-insoluble residue) in the soil environment. The relative reactivity of water-insoluble residues in a range of partially acidulated phosphate rock (PAPR) fertilizers was assessed according to chemical solubility, and was found to be lower than the corresponding original PRs. Two causes were identified for the reduced formic acid solubility of water-insoluble residues: (i) some preferential dissolution of more reactive apatite components (i.e. higher carbonate substituted apatite) during partial acidulation as indicated by reductions in the molar apatite C:P ratio of the residual PRs compared with the corresponding original PRs, and (ii) acid-insoluble metal (Fe-Al-Mg)phosphate and/or fluoride complexes formed on the surface of residual PRs during partial acidulation with commercial-grade phosphoric acid, which were partially soluble in alkaline ammonium citrate. These two mechanisms accounted for most of the solubility differences observed for 'medium' reactive PRs (Khouribga, Arad), compared with only half for more reactive PRs (North Carolina, Gafsa). The conclusion from this study is that partial acidulation may not be an ideal method for the manufacture of fertilizers containing fast and slow release (i.e. PR) components, particularly when highly reactive PRs such as North Carolina are used.

Glasshouse comparison of North Carolina phosphate rock, alkali-treated Christmas Island phosphate rock and single superphosphate as P fertilizers on an acidic soil

1992 ◽  
Vol 43 (7) ◽  
pp. 1667 ◽  
Author(s):  
MJ McLaughlin ◽  
PR Dann ◽  
TR James ◽  
DL Garden
Keyword(s):  
North Carolina ◽  
Phosphate Rock ◽  
Acidic Soil ◽  
Ammonium Citrate ◽  
Residual Value ◽  
Single Superphosphate ◽  
Christmas Island ◽  
Fertilizer Application Rate ◽  
Significant Difference ◽  
P Recycling

Three fertilizers were compared for their P release to pasture species growing on an acidic soil under glasshouse conditions. The fertilizers were a reactive apatitic phosphate rock (North Carolina, NCPR), a KOH-treated crandallite/millisite/goethite phosphate rock (Christmas Island C-grade ore, KC) and single superphosphate (SSP). Four successive crops were grown after an initial application of five rates of each fertilizer. The effect of P recycling on the yield responses to fertilizers was assessed in one set of treatments by replacing P removed in successive herbage harvests with P in sheep dung. NCPR and KC were not as effective as SSP for the first crop, and effectiveness decreased as fertilizer application rate increased. With subsequent crops (24) and for total dry matter production data (crops 1-4 combined) the relative effectiveness of NCPR depended on P recycling treatment. When P was removed at each harvest, NCPR was just as effective as SSP, but KC was less than one third as effective as SSP. When P was recycled after each harvest, NCPR was less effective than SSP, and KC was at best only one-third as effective as SSP. After three crops, the residual value of the three fertilizers was assessed against crop response to a fresh application of SSP. Residual value of all fertilizers was significantly increased by recycling P to the pots. KC had a significantly lower residual value than the other fertilizers, but there was no significant difference between the residual value of initially applied SSP and NCPR. Solubility of P in the SSP and KC fertilizers as measured by water and neutral ammonium citrate was well correlated with plant response to the fertilizers, while the performance of NCPR was underestimated by these methods.

Effect of fertiliser type on cadmium and fluorine concentrations in clover herbage

1997 ◽  
Vol 37 (8) ◽  
pp. 1019 ◽  
Author(s):  
M. J. McLaughlin ◽  
P. G. Simpson ◽  
M. K. Smart ◽  
N. Fleming ◽  
D. P. Stevens ◽  
...  
Keyword(s):  
North Carolina ◽  
Phosphate Rock ◽  
Partially Acidulated Phosphate Rock ◽  
Single Superphosphate ◽  
North Carolina Phosphate Rock ◽  
Reactive Phosphate ◽  
Reactive Phosphate Rock

Summary. This study investigated whether changing phosphatic fertiliser type affects the accumulation of cadmium (Cd) and fluorine (F) in pasture herbage. North Carolina phosphate rock, and partially acidulated fertilisers derived from this rock, generally have higher Cd and F concentrations compared with single superphosphate currently manufactured in Australia. Clover herbage from sites of the National Reactive Phosphate Rock trial was collected and analysed for concentrations of Cd (11 sites) and F (4 sites). A comparison was made between pastures fertilised with 4 rates of single superphosphate, North Carolina phosphate rock, and partially acidulated phosphate rock having Cd concentrations of 283, 481 and 420 mg/kg P respectively, and F concentrations of 170, 271 and 274 g/kg P respectively. One site used Hamrawein (Egypt) phosphate rock (HRP) having a Cd and F concentration of 78 mg Cd/kg P and 256 g F/kg P respectively. To help identify differences in herbage Cd concentrations between sites, unfertilised soils from each site were analysed for total and extractable Cd contents. At one site Cd concentrations in bulk herbage (clover, grasses and weeds) were related to infestation of the pasture by capeweed (Arctotheca calendula L. Levyns). There were no significant differences between F in herbage from plots fertilised with either single superphosphate, partially acidulated phosphate rock or North Carolina phosphate rock, or between sites. Concentrations of F in herbage were low, generally less than 10 mg/kg. However, there were large differences in Cd concentrations in herbage between sites, while differences between fertiliser treatments were small in comparison. The site differences were only weakly related to total or extractable (0.01 mol CaCl2/L) Cd concentrations in soil. Significant differences in Cd concentrations in clover due to fertiliser type were found at 5 sites. North Carolina phosphate rock treatments had significantly higher Cd concentrations in clover compared with single superphosphate at 2 sites. Partially acidulated phosphate rock treatments had significantly higher Cd concentrations in clover compared with single superphosphate at 4 sites. At the site where Hamrawein was tested, this treatment had significantly lower Cd concentrations in clover compared with both single superphosphate and North Carolina phosphate rock treatments.

The agronomic effectiveness of reactive phosphate rocks 1. Effect of the pasture environment

1997 ◽  
Vol 37 (8) ◽  
pp. 921 ◽  
Author(s):  
P. W. G Sale ◽  
R. J. Gilkes ◽  
M. D. A. Bolland ◽  
P. G. Simpson ◽  
D. C. Lewis ◽  
...  
Keyword(s):  
North Carolina ◽  
Phosphate Rock ◽  
Surface Soil ◽  
Annual Rainfall ◽  
Triple Superphosphate ◽  
Agronomic Effectiveness ◽  
P Sorption ◽  
Reactive Phosphate ◽  
Reactive Phosphate Rock ◽  
Very High

Summary. The agronomic effectiveness of directly applied North Carolina reactive phosphate rock was determined for 4 years from annual dry matter responses at 26 permanent pasture sites across Australia as part of the National Reactive Phosphate Rock Project. Fertiliser comparisons were based on the substitution value of North Carolina reactive phosphate rock for triple superphosphate (the SV50). The SV50 was calculated from fitted response curves for both fertilisers at the 50% of maximum yield response level of triple superphosphate. The reactive phosphate rock was judged to be as effective as triple superphosphate in the 1st year (and every year thereafter) at 4 sites (SV50 >0.9), and was as effective by the 4th year at 5 sites. At another 9 sites the reactive phosphate rock was only moderately effective with SV50 values between 0.5 and 0.8 in the 4th year, and at the final 8 sites it performed poorly with the 4th year SV50 being less than 0.5. Pasture environments where the reactive phosphate rock was effective in the 1st year were: (i) those on sandy, humic or peaty podsols with an annual rainfall in excess of 850 mm; (ii) those on soils that experienced prolonged winter inundation and lateral surface flow; and (iii) tropical grass pastures in very high rainfall areas (>2300 mm) on the wet tropical coast on North Queensland. The highly reactive North Carolina phosphate rock became effective by the 4th year at sites in southern Australia where annual rainfall exceeded 700 mm, and where the surface soil was acidic [pH (CaCl2) <5.0] and not excessively sandy (sand fraction in the A1 horizon <67%) but had some phosphorus (P) sorption capacity. Sites that were unsuitable for reactive phosphate rock use in the medium term (up to 4 years at least) were on very high P-sorbing krasnozem soils or high P-sorbing lateritic or red earth soils supporting subterranean-clover-dominant pasture, or on lower rainfall (< 600 mm) pastures growing on soils with a sandy A1 horizon (sand component >84%). No single environmental feature adequately predicted reactive phosphate rock performance although the surface pH of the soil was most closely correlated with the year-4 SV50 (r = 0.67). Multiple linear regression analysis found that available soil P (0–10 cm) and the P sorption class of the surface soil (0–2 cm), together with annual rainfall and a measure of the surface soil"s ability to retain moisture, could explain about two-thirds of the variance in the year-4 SV50 . The results from this Project indicate that there are a number of specific pasture environments in the higher rainfall regions of Australia where North Carolina reactive phosphate rock can be considered as an effective substitute P fertiliser for improved pasture.

scholarly journals Field evaluation of water or citrate soluble phosphorus in modified phosphate rocks for soybean

2001 ◽  
Vol 58 (1) ◽  
pp. 165-170 ◽  
Author(s):  
Luís Ignácio Prochnow ◽  
José Francisco da Cunha ◽  
Ariel Francisco Candiotti Ventimiglia
Keyword(s):  
Field Evaluation ◽  
Water Soluble ◽  
Ammonium Citrate ◽  
Low Grade ◽  
Triple Superphosphate ◽  
Single Superphosphate ◽  
Standard Source ◽  
Extractable P ◽  
P Fertilizers ◽  
P Sources

Ten P fertilizers were collected (commercial fertilizers) or synthesized (experimental sources) in order to obtain single superphosphates varying in water and citrate solubility. A standard source of P was also produced by crystallization of the water-soluble fraction of a triple superphosphate. Eleven P sources were band applied to a medium textured Xanthic Hapludox, in Bahia, Brazil (low content of resin-extractable P) at a rate of 80 kg ha-1 of NAC + H2O (neutral ammonium citrate plus water) soluble P2O5, with soybean as the crop which was grown to maturity. A check plot (control) was included in the study. Three of the P sources [single superphosphate produced from Araxa phosphate rock (PR), low-grade single superphosphate produced from Lagamar PR and the standard source of P] were also applied at rates to provide 40 and 120 kg ha-1 of NAC + H2O soluble P2O5. Yield of soybean was evaluated by analysis of variance with mean comparison performed utilizing LSD lines, considering the P sources applied at a rate of 80 kg ha-1 of P2O5 + control. Regression procedures were used to study the relation between yield of soybean and rates of P2O5. The fertilizers tested performed equally well as a source of P for soybean. The level of water-soluble P did not influence fertilizer performance.

scholarly journals Ozone Reacts With Carbon Black to Produce a Fulvic Acid-Like Substance and Increase an Inflammatory Effect

2020 ◽  
Vol 48 (7) ◽  
pp. 887-898
Author(s):  
Andrew J. Ghio ◽  
David H. Gonzalez ◽  
Suzanne E. Paulson ◽  
Joleen M. Soukup ◽  
Lisa A. Dailey ◽  
...  
Keyword(s):  
Carbon Black ◽  
Fulvic Acid ◽  
Water Soluble ◽  
Ozone Exposure ◽  
Ammonium Citrate ◽  
Ferric Ammonium Citrate ◽  
Air Exposure ◽  
Carbonaceous Particle ◽  
Carbonaceous Particles ◽  
Inflammatory Effect

Exposure to ambient ozone has been associated with increased human mortality. Ozone exposure can introduce oxygen-containing functional groups in particulate matter (PM) effecting a greater capacity of the particle for metal complexation and inflammatory effect. We tested the postulate that (1) a fulvic acid-like substance can be produced through a reaction of a carbonaceous particle with high concentrations of ozone and (2) such a fulvic acid-like substance included in the PM can initiate inflammatory effects following exposure of respiratory epithelial (BEAS-2B) cells and an animal model (male Wistar Kyoto rats). Carbon black (CB) was exposed for 72 hours to either filtered air (CB-Air) or approximately 100 ppm ozone (CB-O3). Carbon black exposure to high levels of ozone produced water-soluble, fluorescent organic material. Iron import by BEAS-2B cells at 4 and 24 hours was not induced by incubations with CB-Air but was increased following coexposures of CB-O3 with ferric ammonium citrate. In contrast to CB-Air, exposure of BEAS-2B cells and rats to CB-O3 for 24 hours increased expression of pro-inflammatory cytokines and lung injury, respectively. It is concluded that inflammatory effects of carbonaceous particles on cells can potentially result from (1) an inclusion of a fulvic acid-like substance after reaction with ozone and (2) changes in iron homeostasis following such exposure.

Sign in / Sign up

Export Citation Format

Share Document