Total Phosphorus and Reactive Phosphate Removal from Aquaculture Wastewater using Calcined Eggshell

Phosphorus is the key nutrient in fish feed, and it has been one of the major soluble nutrients found in aquaculture wastewater (AW). This work aims to evaluate the removal of Total Phosphorus (TP) and Reactive Phosphate (PO4 3-) via adsorption in batch studies using thermally calcined eggshell as adsorbent. The effect of calcination temperature (700 – 1000°C), particle size and holding time were investigated. The screening phase showed that calcined eggshell at 800 °C for 30 minutes was the most suitable condition. Characterization of adsorbents revealed that crystalline structure and functional groups were responsible for the TP and PO4 3- removal using calcined eggshell from AW. Adsorption equilibrium was attained after 15 min with the dosage of 0.2 g of the optimized adsorbent, capable of removing more than 97 % of TP and PO4 3- from AW. This finding has proven the ability of calcined eggshell waste as a potential phosphorus adsorbent from liquid effluents.

Ammonium sulfate enhances the effectiveness of reactive natural phosphate for fertilizing tropical grasses

Reactive natural phosphate is a slow and gradual solubilizing fertilizer, which makes it difficult to use in neutral to alkaline soils. Nitrogen fertilizers which acidify the soil may increase the possibility of using this phosphate fertilizer commercially. Two greenhouse experiments were conducted to compare responses of Xaraés palisadegrass (Urochloa brizantha syn. Brachiaria brizantha cv. Xaraés) and Mombasa guineagrass (Megathyrsus maximus syn. Panicum maximum cv. Mombasa), when different combinations of P and N fertilizers were applied during the establishment phase in non-acidic soils or with corrected acidity. The experiments were carried out in a completely randomized design with 3 fertilizer combinations (simple superphosphate plus urea, SSU; natural reactive phosphate plus urea, RPU; and natural reactive phosphate plus ammonium sulfate, RPAS). There was no difference in tiller density, leaf numbers, forage mass, leaf mass and stem mass for either forage on SSU and RPAS treatments but they exceeded those on RPU. Soil pH was lower in soil fertilized with ammonium sulfate than in soil fertilized with urea. Applying natural reactive phosphate plus ammonium sulfate seems as effective as simple superphosphate plus urea in promoting increased growth in tropical grasses on low-P soils. Longer-term and more extensive field studies are needed to determine if these results can be reproduced in the long term, and the level of soil acidification over time.

Study on Characteristics of Nitrogen and Phosphorus Loss under an Improved Subsurface Drainage

Agricultural drainage plays an effective role in preventing waterlogging and salinity disasters and also is the main transport pathway for agricultural non-point source pollutants into rivers and lakes. Hence, the water quality of agricultural drainage should be a point of focus. In this paper, nitrogen and phosphorus loss under improved subsurface drainage with different filter materials (gravel, layered sand-gravel, mixed sand-gravel, straw) were studied by a three-year field experiment (2016–2018) compared with the conventional subsurface drainage. The pH values, total nitrogen, ammonia nitrogen, nitrate nitrogen, total phosphorus and soluble reactive phosphate were considered. The results showed that the nitrogen and phosphorus concentrations of drain outflow under improved subsurface drainage with gravel filter were larger than that with layered sand-gravel filter and mixed sand-gravel filter. The improved subsurface drainages with layered sand-gravel filter and mixed sand-gravel filter had an effect on reducing the ammonia nitrogen, total phosphorus and soluble reactive phosphate concentrations of the outflow. Meanwhile, the characteristics of nitrogen and phosphorus loss under the improved subsurface drainage with straw filter were different from that with layered sand-gravel filter and mixed sand-gravel filter. For the improved subsurface drainage with layered sand-gravel filter outflow, the ammonia nitrogen, total phosphorus, and soluble reactive phosphate concentrations were about 13%–78%, 38%–63%, 40%–68% less, and total nitrogen, nitrate nitrogen concentrations were 24%–80%,18%–96% more than that under conventional subsurface drainage. Meanwhile, for the improved subsurface drainage with straw filter outflow, compared with conventional subsurface drainage outflow, the percentage changes of the total nitrogen, nitrate nitrogen, ammonia nitrogen, total phosphorus and the soluble reactive phosphate concentrations were about −76%–62%, −77%–78%, −152%–−274%, −103%–−400% and −221%–−291%, respectively. Additionally, in the outflow of all subsurface drainage patterns, there were much higher total nitrogen and nitrate nitrogen concentrations which should be focused on and the agricultural water management should be adopted.

Seasonal and Spatial Variation of Dissolved Oxygen and Nutrients in Padaviya Reservoir, Sri Lanka

Lakes, reservoirs, rivers, and aquifers are important freshwater sources for basic human needs such as drinking, sanitation, and agriculture. The anthropogenic influences on the natural environment, especially on freshwater resources, have increased dramatically during the last few decades. Eutrophication and pollution are major threats to many of these water bodies. There are thousands of man-made reservoirs, which are centuries old in Sri Lanka, and only a handful of them have been extensively studied and monitored. This study investigates the spatial and seasonal variations of water quality in Padaviya Reservoir by studying the vertical distribution of physical parameters and inorganic nitrogen species: ammonia, nitrite and nitrate, reactive phosphate, and dissolved oxygen. Padaviya Reservoir, which is an ancient man-made irrigation reservoir, has never been studied in detail to assess its water quality. Sharp chemical gradients for ammonia, nitrite, nitrate, reactive phosphate, and dissolved oxygen were observed between surface and bottom waters of the reservoir, suggesting that it does not overturn completely. The temperature difference is between the surface and bottom waters of about 2°C, which is not large enough to cause thermal stratification. The most probable reason for the stratification is extensive photosynthesis at surface waters with subsequent decomposition of the organic material at the bottom.

Novel Fe3O4 nanoparticles-based DGT device for dissolved reactive phosphate measurement

The use of Fe3O4 nanoparticles as a liquid binding phase in DGT is demonstrated for the sampling measurement of dissolved reactive phosphate in natural water.