EFFECTS OF VARIOUS PROCESS PARAMETERS ON TEMPERATURE PROFILE OF ADIABATIC FIXED BED REACTOR FOR PRODUCTION OF DIMETHYL ETHER (DME) FROM METHANOL

2007 ◽  
Vol 194 (11) ◽  
pp. 1495-1502 ◽  
Author(s):  
Ali Eliassi ◽  
Lotfollah Savadkoohi ◽  
Ali Kargari
2011 ◽  
Vol 347-353 ◽  
pp. 3681-3684 ◽  
Author(s):  
Young Ho Kim ◽  
Su Gyung Lee ◽  
Byoung Kwan Yoo ◽  
Han Sol Je ◽  
Chu Sik Park

A SAPO-34 catalyst is well known to be one of the best catalysts for DME to olefins (DTO) reaction. Main products of the reaction were light olefins such as ethylene, propylene and butenes. However, the main problem is rapid deactivation of the SAPO-34 catalyst due to coke deposition during DTO reaction. In this study, various SAPO-34/ZrO2 catalysts added with ZrO2 were prepared for improving the lifetime and their physicochemical properties have been characterized by XRD and SEM. The DTO reaction over various SAPO-34/ZrO2 catalysts was carried out using a fixed bed reactor. All SAPO-34/ZrO2 catalysts showed similar activity and selectivity in the DTO reaction. The SAPO-34(9wt%)/ZrO2 catalyst was showed the best performance for the catalyst lifetime.


2019 ◽  
Vol 33 (11) ◽  
pp. 11226-11234 ◽  
Author(s):  
Mehrdad Seifali Abbas-Abadi ◽  
Maryam Fathi ◽  
Mohammad Ghadiri

2013 ◽  
Vol 15 (2) ◽  
pp. 122-127 ◽  
Author(s):  
Ziyang Bai ◽  
Hongfang Ma ◽  
Haitao Zhang ◽  
Weiyong Ying ◽  
Dingye Fang

The production processes included catalytic dehydration of methanol in an adiabatic fixed-bed reactor and two columns product separations. In this study, the technological process for dimethyl ether (DME) synthesis is built on PRO/II platform based on the combined parameters of the reaction dynamic model for methanol dehydration reaction, the improved NRTL model of the liquid phase, the PR model of vapor phase. In order to validate the proposed model, the simulation results have been compared with the available data from a set of industrial production equipment with a production capacity of 200 000 tonnes per annum. A comparison between the calculated and measured results has proved that these results are satisfactory. The bed height and the volume of the catalytic bed are calculated aim at one million t/a DME yields and while taking account of high-purity DME production. After discussing the influence of feed stage location and reflux ratio for DME product purity, the suitable unit operation conditions are chosen. Accordingly, accurate process simulation results provide the basis and guidance for an improvement and development of the similar industrial device.


2014 ◽  
Vol 70 (2) ◽  
pp. 1228-1237 ◽  
Author(s):  
Flavio Manenti ◽  
Andres R. Leon-Garzon ◽  
Zohreh Ravaghi-Ardebili ◽  
Carlo Pirola

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