ELECTRICAL PROPERTIES OF SILICONE OIL-WATER INTERFACE IN THE PRESENCE OF IONIC SURFACTANTS AND SALT: IMPORTANCE IN THE STABILITY OF OIL-IN-WATER EMULSIONS

2014 ◽  
Vol 201 (12) ◽  
pp. 1645-1663 ◽  
Author(s):  
Krishnamurthy Sainath ◽  
Pallab Ghosh
2013 ◽  
Vol 319 ◽  
pp. 233-238 ◽  
Author(s):  
De Hai Yu ◽  
Zhao Yun Lin ◽  
You Ming Li

Octadecenylsuccinic anhydride (ODSA) is an internal sizing agent used to hydrophobize paper and paper board in the process of papermaking. Nano-montmorillonite (MMT) particles and n-dodecane were used as the stabilizer to prepare stable ODSA Pickering emulsions. The effects of pH value, particle concentration, hydrolysis resistance and paper sizing performance of the ODSA Pickering emulsions were investigated. It was found that the stability of ODSA emulsions first increased and then decreased as the pH value decreased. More stable oil-in-water (o/w) emulsion can be made using 10 vol.% n-dodecane. Particle concentration was linked to the formation of particle films at oil–water interface, with a required minimum particle concentration of 1.5 wt.%. Paper sizing degree analysis indicated that the ODSA Pickering emulsions show increased hydrolysis resistance and good sizing performance.


2015 ◽  
Vol 104 (4) ◽  
pp. 1282-1290 ◽  
Author(s):  
Shyam B. Mehta ◽  
Rachael Lewus ◽  
Jared S. Bee ◽  
Theodore W. Randolph ◽  
John F. Carpenter

Adsorption ◽  
2019 ◽  
Vol 25 (4) ◽  
pp. 903-911
Author(s):  
Jolanta Narkiewicz-Michalek ◽  
Marta Szymula ◽  
Sonia Losada-Barreiro ◽  
Carlos Bravo-Diaz

1991 ◽  
Vol 40 (7) ◽  
pp. 561-565
Author(s):  
Masao NAKAMURA ◽  
Hajime HATTORI ◽  
Tadahiko KIDOKORO ◽  
Tsutomu SEIMIYA

2021 ◽  
Vol 43 (5) ◽  
pp. 520-520
Author(s):  
Samuel Olalekan Olusanya Samuel Olalekan Olusanya ◽  
Gbenga Joseph Adebayo Gbenga Joseph Adebayo ◽  
Samuel Olutayo Afolabi and Adewumi Oluwasogo Dada Samuel Olutayo Afolabi and Adewumi Oluwasogo Dada

The preparation of vegetable oil-water emulsions stabilized by soybean protein and microgel is described. The soybean protein was obtained from n-hexane-defatted soybean powder using a Soxhlet extractor. Using equal volumes of oil and water, vegetable oil-water emulsions were formed either by handshaking the mixture or homogenizing the mixture using a Lab homogenizer. The emulsion was characterized using a drop test and microscopy observation. The drop test shows that the preferred emulsion is vegetable oil-in-water (o/w). The effect of salt and emulsifier concentration on the stability and emulsion drop size was investigated. Emulsions stabilized by soybean protein without addition of salt breakdown after 3 days of preparation because of decomposition of the protein. For emulsions stabilized by microgel in the absence of salt, phase separation occurred within 1 hour. At a fixed salt concentration, it was found that increasing the emulsifier concentration has a significant effect on the stability and drop size of the emulsions stabilized by both protein and microgel. For emulsions stabilized by soybean protein, the stability of emulsions increased with increasing salt concentration without any significant influence on the drop size. The results obtained from the surface tension measurement revealed that different mechanisms of stabilization exist in emulsions stabilized by the protein and microgel.


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