Photo-catalytic degradation of sulfamethoxazole from aqueous solutions using Cu-TiO2/ CQDs hybrid composite, optimisation, performance and reaction mechanism studies

Author(s):  
Roghayeh Noroozi ◽  
Mitra Gholami ◽  
Roshanak Rezaei Kalantary ◽  
Mahdi Farzadkia
2017 ◽  
Vol 17 (3) ◽  
pp. 439 ◽  
Author(s):  
Roto Roto ◽  
Marcelina Marcelina ◽  
Nurul Hidayat Aprilita ◽  
Mudasir Mudasir ◽  
Taufik Abdillah Natsir ◽  
...  

Analysis of Fe3+ ion present in aqueous solutions is always of interests. Recently, this ion has been analyzed by colorimetric methods using colloid of silver nanoparticles (AgNPs) in capping agents of polymers. The reaction mechanism between AgNPs and Fe3+ is still subject to the further investigation. In this work, 1,10-phenanthroline was used to probe the reaction mechanism between AgNPs and Fe3+ ion in the solution. The colloids of AgNPs were prepared in the polyvinyl alcohol (PVA) solution and reacted with Fe3+. The colloid surface plasmon absorbance decreases linearly along with the increase in Fe3+ concentration. The addition of 1,10-phenanthroline to mixture changes the solution to red, indicating that the reaction produces Fe2+. This suggests that the reduction of the AgNPs absorbance is the result of oxidation of the Ag nanoparticles along with the reduction of Fe3+.


2019 ◽  
Vol 42 (4) ◽  
Author(s):  
Juan A Torres-Luna ◽  
Gloria I Giraldo-Gómez ◽  
Nancy R Sanabria-González ◽  
José G Carriazo

2007 ◽  
Vol 2 (4) ◽  
pp. 354-358
Author(s):  
Dazhang Zhu ◽  
Shilong Wang ◽  
Xiaoyu Sun ◽  
Yaming Ni ◽  
Side Yao

1992 ◽  
Vol 57 (2) ◽  
pp. 268-275 ◽  
Author(s):  
El-Sayed M. Mabrouk ◽  
Hamada M. Killa ◽  
Abdel Fattah A. Abdel Fattah ◽  
Shalaby A. Yasen

The polarographic and cyclic voltammetric behaviour of (2-hydroxyphenylazo)-4-benzenesulfonamide and some of its derivatives have been studied in Britton-Robinson buffer series containing 30 vol.% of DMF. Over the entire pH range (2-12), the reduction pathway occurs through an irreversible 4-electron step corresponding to the reduction of N=N center to the amine stage. The voltammograms recorded in acidic and alkaline solution at different scan rates exhibit one or two cathodic peaks depending on the substituent and the pH of the medium. The electrode reaction mechanism was suggested, also the kinetic parameters were calculated.


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