The excitation of
γ
-rays by the impact of
β
-rays on different substances has been investigated by several observers. The question was first systematically examined by J. A. Gray. He showed that penetrating
γ
-rays are produced by the
β
-rays of radium E when they impinge on different materials, the amount of
γ
-radiation increasing with increase of atomic weight of the material. The particular disposition used in his first experiments was not suitable for the examination of any soft types of radiation which might have been excited, but in later work he showed, for the first time, that characteristic radiations were excited in the case of silver, tin, barium and cerium. Chadwick, using the balance method of Rutherford and Chadwick, examined whether the
β
-rays from radium B and radium C excite penetrating
γ
-rays in different kinds of matter. Definite evidence was obtained that an excited radiation amounting to about 0.5 per cent, of the primary
γ
-radiation is produced. This method, however, was not suitable for the detection of soft characteristic radiations. These general results have recently been confirmed by Starke, using the
β
-rays from a strong preparation of mesothorium. In previous papers by Rutherford and the author on the analysis of the
γ
-rays from radioactive substances, it has been shown that the
γ
-rays emitted by the different products can be separated into groups differing widely in penetrating power. Some of these radiations appear to be characteristic of the elements by which they are emitted and fall into one or other of the series given by Barkla. On the other hand, some of the groups of rays found do not appear to belong to either series. It was further shown in previous work that when radium C is deposited on nickel a soft radiation is given out which is entirely absorbed by 2 mm. of aluminium. This soft radiation was much more readily absorbed than that emitted by radium B, and for which
μ
= 40 (cm.
-1
), but it was appreciably harder than the characteristic radiation of nickel. Moreover, when radium C was deposited on silver, little, if any, soft radiation appeared to be emitted. It seemed of importance, therefore, to examine in detail the nature of the radiation excited by the
β
- and
γ
-rays from radium B and radium C, and to examine the bearing of the results on the type of radiation emitted by different materials on which radium C is deposited.