Development of computational methods for estimation of current efficiency and cell voltage in a Chlor-alkali membrane cell

Author(s):  
Alexei Valerievich Yumashev ◽  
Seyed Morteza Fateminasab ◽  
Azam Marjani ◽  
Amin B. Lirgeshas
2019 ◽  
Vol 25 (33) ◽  
pp. 43-56 ◽  
Author(s):  
Narjes Shojaikaveh ◽  
Seyed Nezamedin Ashrafizadeh ◽  
Fereydoon Mohammadi ◽  
Amin Amerighasrodashti

2013 ◽  
Vol 828 ◽  
pp. 45-54 ◽  
Author(s):  
Anupam Agnihotri ◽  
Shail Umakant Pathak ◽  
Jyoti Mukhopadhyay

The Hall-Heroult process for the production of aluminium is based on the electrochemical reduction of alumina (Al2O3) dissolved in a cryolite (Na3AlF6) based electrolyte. Instability in cell voltage is referred to as noise. Normal voltage noise is inevitable due to bubble evolution and it has little effect on performance parameters such as, current efficiency and power consumption. Metal rolling noise (wavy noise) is caused by the disturbances in cell magnetic field and it affects the cell current efficiency adversely. Investigating the causes of the cell instability in the aluminium smelting cells can lead to better cell performance. Understanding the variation in cell voltage is critical for cells, because magnitude of voltage determines the energy consumption pattern in the process and hence, any saving on voltage can save energy. Voltage affects the current efficiency of the cell and an optimum cell voltage leads to higher current efficiency without compromising on energy consumption. Magnetic, current distribution, heat loss and voltage at zero current measurements along with online current and voltage signal can help to identify the problems and their combined effects on the performance of the cells. In order to estimate the loss in current efficiency of the aluminum electrolysis cells due to metal instabilities, measurements were performed and data analyzed. The present paper analyses the effect of voltage fluctuations (noise) during metal instability along with cause of instability and its effect on current efficiency of the cell. Measurements carried out to estimate the deviations from the normal cell operations are also discussed.


1979 ◽  
Vol 18 (1) ◽  
pp. 13-18 ◽  
Author(s):  
C. Castellano ◽  
D. Bratland ◽  
K. Grjotheim ◽  
T. Müftüoglu ◽  
J. Thonstad

2015 ◽  
Vol 1120-1121 ◽  
pp. 141-147
Author(s):  
Zhong Gui Li ◽  
Ting Jin Zhou ◽  
Ri Yao Chen ◽  
Xiao Chen ◽  
Xi Zheng ◽  
...  

The polyacrylonitrile (PAN)-iron octocarboxyphthalocyanine (FePc(COOH)8) nanofibers were prepared using electrospinning technique and introduced into the interlayer of a carboxymethyl cellulose (CMC)-polyvinyl alcohol (PVA)/chitosan (CS)-polyvinyl alcohol bipolar membrane (BPM), which was characterized using SEM, contact angle measurement, current-voltage characteristics, AC impedance spectroscopy and so on. The experimental results showed that after modification by PAN-FePc(COOH)8 nanofibers, the membrane impedance of the BPM and its cell voltage were decreased. That indicated that the water splitting efficiency in the interlayer of the BPM was increased. Then the prepared CMC-PVA/PAN-FePc(COOH)8/CS-PVA BPM was used in the electro-oxidized preparation of dialdehydle starch (DAS). The experimental results indicated that a current density of 20mA·cm-2 was suitable to obtain high current efficiency. When the electrolysis time was 3h at a current density of 20 mA·cm-2 , the current efficiency of the CMC-PVA/PAN-FePc(COOH)8/CS-PVA BPM-equipped cell was as high as 67%.


Sign in / Sign up

Export Citation Format

Share Document