Performance of different ionic liquids to remove phenol from aqueous solutions using supported liquid membrane

2014 ◽  
Vol 54 (11) ◽  
pp. 3062-3072 ◽  
Author(s):  
Santhi Raju Pilli ◽  
Tamal Banerjee ◽  
Kaustubha Mohanty
2010 ◽  
Vol 33 (13) ◽  
pp. 2002-2009 ◽  
Author(s):  
Tatjana M. Trtić-Petrović ◽  
Ksenija R. Kumrić ◽  
Jelena S. Đorđević ◽  
Goran T. Vladisavljević

2014 ◽  
Vol 68 (4) ◽  
Author(s):  
Noura Kouki ◽  
Rafik Tayeb ◽  
Mahmoud Dhahbi

AbstractA flat sheet-supported liquid membrane (FSSLM) system, consisting of an ionic liquid, tricapryl-methylammonium chloride (Aliquat 336®) in octan-2-ol, is proposed as a means of recovering acetaminophen (Ac) from aqueous solutions; Ac is an active ingredient widely used in many pharmaceutical preparations. Several parameters which could affect the transport efficiency were examined, i.e., the strippant nature and concentration in the receiving solution, the diluent nature, carrier concentration, initial acetaminophen concentration in the feed solution, and the polymeric support type. A facilitated transport was obtained by impregnating the polymeric support with 10 vol. % of Aliquat 336® in octan-2-ol, 1 M NaOH as a receiving solution, and a feed solution of Ac dissolved in ultrapure water. The study was completed by using the FSSLM thus developed for extracting Ac from some drugs in frequent use in Tunisia (Analgan®, Doliprane®, and Fervex®).


2017 ◽  
Vol 75 (10) ◽  
pp. 2358-2368 ◽  
Author(s):  
Jakub Rajewski ◽  
Paulina Rajewska

This paper describes the problem of recovery and reusing chromium from aqueous solutions. The authors studied a novel double-carrier supported liquid membrane system (DCSLM) with di(2-ethylhexyl) phosphoric acid (D2EHPA) and bis(2,4,4-trimethyl) phosphinic acid (Cyanex272) as a carrier of Cr(III) ions as a method to separate chromium (III) from acid solutions. As a result, they confirmed that the presence of two carriers in the DCSLM with the most effective carrier concentration ratios, leads to approximately three times shorter pertraction, compared to a process conducted with the D2EHPA only. It was found that synergistic effect is independent of the initial concentration of chromium in the feed solution. Higher initial concentrations of Cr(III) ≥ 0.01 mol dm−3 cause high ‘exhaustion’ of active carrier molecules at the interface. Moreover, the authors observed the increase in viscosity in the membrane phase and process inhibition. It was found that efficiency of separation of chromium ions from aqueous solutions using a liquid membrane depends on the transport rate for these ions in the membrane (ions pertraction). Therefore, it was concluded that the pertraction stage of the Cr(III) ions limits the efficiency of the whole separation process.


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