An overview on nanostructure-modified supported liquid membranes for the electromembrane extraction method

The efficiency of electromembrane extraction can be improved by modification of supported liquid membrane with various nanomaterials.

Prediction of Nickel Removal using Diffusion Model in Flat Sheet Supported Liquid Membrane

Supported liquid membrane (SLM) is one of the potential extraction methods for the treatment of wastewater containing various toxic heavy metal ions. Advantageously, this process offers simultaneous removal and recovery, as well as low energy consumption and operational cost. In this study, the prediction of nickel removal was investigated using a diffusion model developed through MATLAB.

Separation Iron(III)-Manganese(II) via Supported Liquid Membrane Technology in the Treatment of Spent Alkaline Batteries

In this paper, the transport of iron(III) from iron(III)-manganese(II)-hydrochloric acid mixed solutions, coming from the treatment of spent alkaline batteries through a flat-sheet supported liquid membrane, is investigated (the carrier phase being of Cyanex 923 (commercially available phosphine oxide extractant) dissolved in Solvesso 100 (commercially available diluent)). Iron(III) transport is studied as a function of hydrodynamic conditions, the concentration of manganese and HCl in the feed phase, and the carrier concentration in the membrane phase. A transport model is derived that describes the transport mechanism, consisting of diffusion through a feed aqueous diffusion layer, a fast interfacial chemical reaction, and diffusion of the iron(III) species-Cyanex 923 complex across the membrane phase. The membrane diffusional resistance (Δm) and feed diffusional resistance (Δf) are calculated from the model, and their values are 145 s/cm and 361 s/cm, respectively. It is apparent that the transport of iron(III) is mainly controlled by diffusion through the aqueous feed boundary layer, this being the thickness of this layer calculated as 2.9 × 10−3 cm. Since manganese(II) is not transported through the membrane phase, the present system allows the purification of these manganese-bearing solutions.

Separation Fe(III)-Mn(II) via Supported Liquid Membrane Technology in the Treatment of Spent Alkaline Batteries

The transport of iron(III) from Fe(III)-Mn(II)-HCl mixed solutions through a flat-sheet supported liquid membrane is investigated, being the carrier phase of Cyanex 923 (commercially available phosphine oxide extractant) dissolved in Solvesso 100 (commercially available diluent), as a function of hydrodynamic conditions, concentration of manganese and HCl in the feed phase, and carrier concentration in the membrane phase. A transport model is derived that describes the transport mechanism, consisting of diffusion through a feed aqueous diffusion layer, a fast interfacial chemical reaction, and diffusion of the Fe(III)-Cyanex 923 complex across the membrane phase. The membrane diffusional resistance (Δm) and feed diffusional resistance (Δf) are calculated from the model, and their values are 145 s/cm and 361 s/cm, respectively. It is apparent that the transport of iron(III) is mainly controlled by diffusion through the aqueous feed boundary layer, being the thickness of this layer calculated as 2.9x10-3 cm. Since Mn(II) is not transported through the membrane phase, the present system allows to the purification of this manganese-bearing solutions.