Circular Dichroism assisted bi-directional absorbers

Author(s):  
Yang Cheng ◽  
Yongfeng Li ◽  
He Wang ◽  
Jiafu Wang ◽  
Zhe Qin ◽  
...  

Abstract Chirality, a geometric property that is of great importance in chemistry, biology, and medicine, has spurred many breakthroughs in the field of multi-dimensional metasurfaces that provide efficient ways of flexibly manipulating amplitude and phase of circular polarization (CP) waves. As one of the most important applications, chiral metamaterials can be used to implement novel absorbers. Herein, an ultra-thin wideband circular dichroic asymmetric metasurface was implemented via loading resistive film into chiral resonators. Opposite and reversible polarization conversion and circular dichroism (CD) were realized as being illuminated by CP waves from both sides meanwhile. Theoretical derivation and simulation verify that the polarization conversion and CD enhancement utilizing multi-layer CD metasurface. It is also found that the orientation angle of the meta-atom of each layer plays an important role in the CD enhancement, which paves a new way for CD enhancement. In addition, the coupling between the CD resonators was utilized to manipulate CD. On this basis, an ultra-thin polarization-insensitive absorber was achieved by employing a C4 2×2 CD resonator array, which was identical illuminating from front and back sides. Circular dichroic absorbers possess great potential in practical applications, ranging from stealth technology, antenna isolation, multi-functional microwave devices, chiral sensing, and catalysis.

2021 ◽  
Vol 14 (3) ◽  
pp. 032006
Author(s):  
Chia-Yi Lin ◽  
Yu-Yu Chen ◽  
Pao Tai Lin ◽  
Shih-Hui Gilbert Chang

2017 ◽  
Vol 19 (10) ◽  
pp. 6996-7008 ◽  
Author(s):  
Matthias Schulz ◽  
Majvor Mack ◽  
Oliver Kolloge ◽  
Arne Lützen ◽  
Manuela Schiek

We demonstrate the feasibility of inserting highly circular dichroic active layers into an organic photodiode as a potential detector for circular polarized light.


Author(s):  
Kirill Koshelev ◽  
Yasaman Jahani ◽  
Andreas Tittl ◽  
Hatice Altug ◽  
Yuri Kivshar

In contrast to relatively well developed experimental and theoretical studies on polypeptides and proteins (see Gratzer 1967 and McLachlan 1967, this volume) the investigation of optical activity of polynucleotides and nucleic acids were very restricted. The optical rotatory dispersion curves of polynucleotides examined in the visible and near u. v. fit one-term Drude equation regardless of the conformation (Fresco 1961; Levedahl & James 1957; Ts’o, Helmkamp & Sander 1962). Recent circular dichroism (c. d.) measurements of several polynucleotides and nucleic acids (figure 1) indicated clearly the presence of dichroic bands in the u. v. region of base absorption which can be related to the dissymmetrical helical conformation (Brahms 1963). The intensity of circular dichroic bands decreases strongly under the conditions in which the helical structure is unstable and goes to random coil form (Brahms 1964; Brahms & Mommaerts 1964). Thus polyadenylic acid (poly A ) is known according to X-ray data to exist at acid pH in a helical two strand and right handed conformation (Rich, Davies, Crick & Watson 1961). In acid solution the same polyadenylic acid exhibits strong circular dichroic bands which disappear at high temperature (figure 2).


Micromachines ◽  
2020 ◽  
Vol 11 (7) ◽  
pp. 641
Author(s):  
Gaku Furusawa ◽  
Tetsuo Kan

We propose a thin, single-layered circular dichroic filter with Au nanospiral structures on a polydimethylsiloxane (PDMS) thin film that has strong circular dichroism at visible wavelengths. Au nanospiral structures with a diameter of 70 nm were fabricated by cryogenic glancing angle deposition on a substrate with a nanodot array template patterned with the block copolymer PS-PDMS. The Au nanospiral structures were transferred onto a transparent and flexible PDMS thin film to fabricate a thin, single-layered circular dichroic filter. The filter had a very large circular dichroism peak of −830 mdeg at 630 nm. The results show that the Au nanospiral structures transferred onto PDMS thin film exhibit large circular dichroism at visible wavelengths.


1976 ◽  
Vol 54 (1) ◽  
pp. 70-76 ◽  
Author(s):  
Claudio Toniolo ◽  
Gian Maria Bonora

The contribution to the circular dichroism of L-Ala-L-Ala, L-Nva-L-Nva, L-Val-L-Val, L-Leu-L-Leu, L-Ile-L-Ile, L-Cys(Me)-L-Cys(Me), L-Met-L-Met, and L-Phe-L-Phe internal peptide chromophores in 1,1,1,3,3,3-hexafluoropropan-2-ol were calculated by subtracting the total molar ellipticity values of N- and C-protected homo-trimers from those of the pertinent protected homo-tetramers.The circular dichroism of the internal peptide chromophore of aliphatic hydrocarbon- and sulfur-containing peptides, each of the L-configuration, show a negative band at 2l5–230 nm accompanied by a more intense negative band near 200 nm. A structured weak and negative band near 260 nm along with bands at 240 nm (negative), 222 nm (positive), and 210.5 nm (negative) of progressively increasing intensity are apparent in the circular dichroic spectrum of L-Phe-L-Phe internal peptide chromophore. The effect of solvent polarity is discussed in the case of L-Val-L-Val and L-Ala-L-Ala internal peptide chromophores.Among the protected homo-trimers and tetramers only those of L-alanine are soluble in aqueous solution; consequently, the effect of water as a function of temperature, urea, and guanidinium chloride on the L-Ala-L-Ala internal peptide chromophore circular dichroism was established.


1976 ◽  
Vol 156 (2) ◽  
pp. 469-472 ◽  
Author(s):  
S Demeter ◽  
L Mustardy ◽  
E Machowicz

In greening maize mesophyll, circular dichroism (c.d.) revealed the early formation of protein-chlorophyll complexes, followed by unorganized chlorophyll. The intense c.d. [Gregory & Raps (1974) Biochem. J. 142, 193-201] appeared later still, whereas membrane-membrane contact (stacking), measured from electron micrographs, appeared much earlier. Isolated grana, which still showed stacking, lost 92% of their original intense c.d.; intense c.d. is not therefore simply dependent on stacking.


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