Observation of Griffiths Phase, Critical Exponent Analysis and High Magnetocaloric Effect Near Room Temperature at Low Magnetic Field in V doped La0.7Sr0.3MnO3

2022 ◽  
Author(s):  
Jagadish Kumar Galivarapu ◽  
Ashika Jose ◽  
Erappanal Padmanabhan Jinu ◽  
Thirumalainaidu Thiagarajan Saravanan ◽  
Senthil Kumar Eswaran ◽  
...  
Keyword(s):  
Magnetic Fields ◽  
Curie Temperature ◽  
Critical Exponent ◽  
Critical Exponents ◽  
Room Temperature ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy ◽  
Griffiths Phase ◽  
Vanadium Doping

Abstract We report on observation of Griffiths phase, high magnetocaloric properties at low magnetic fields and temperature dependent critical exponents of La0.7Sr0.3VxMn1-xO3 (x=0, 0.05 & 0.1) perovskite bulk materials. The Curie temperature (TC) of pure La0.7Sr0.3MnO3 is seen to be 368.7 K and decreases towards room temperature (342.2 K) by 10 mol% vanadium doping at the Mn site. Vanadium doping leads to enhancement in magnetic entropy change (-SM) from 1 Jkg-1K-1to 1.41 Jkg-1K-1. Vanadium doping at Mn site leads to the formation of Griffiths phase, a magnetic disorder due to the co-existence of paramagnetic matrix and short range ferromagnetic clusters. X-ray photoelectron spectroscopy analysis confirm the presence of mixed valance V4+/V5+along with Mn3+/ Mn4+ ions contributing to various double exchange interactions. Nature of phase transitions and magnetic interactions are analyzed by evaluating critical exponents and. All the samples show second-order ferromagnetic (FM) to paramagnetic (PM) phase transition, confirmed from the modified Arrott’s plots and critical exponent analysis carried out using Kouvel-Fisher method. Enhancement in magnetic entropy change along with the decrease in Curie temperature towards room temperature by vanadium doping in the La0.7Sr0.3MnO3 oxides indicates the possible application of these materials for the magnetic refrigeration at low magnetic fields.

scholarly journals Magnetic properties of the non-stoichiometric TbCo2Nix alloys

2018 ◽  
Vol 185 ◽  
pp. 04021
Author(s):  
Alexander Inishev ◽  
Evgeny Gerasimov ◽  
Nikolay Mushnikov ◽  
Pavel Terentev ◽  
Vasily Gaviko
Keyword(s):  
Magnetic Properties ◽  
Curie Temperature ◽  
Concentration Dependence ◽  
Magnetic Moment ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy ◽  
Thermodynamic Relation ◽  
Temperature Dependences

The magnetic and magnetothermal properties of the non-stoichiometric TbCo2Nix (0 ≤ x ≤ 0.2) alloys were studied. It was found that the concentration dependence of the Curie temperature and magnetic moment of the 3d-sublattice have a maximum at x = 0.025. The obtained experimental magnetic properties of the TbCo2Nix alloys were discussed under assumption that the Co magnetic moment in the compounds changes with increasing x. The magnetic entropy change was determined using the temperature dependences of the magnetization and Maxwell’s thermodynamic relation. The obtained results for TbCo2Nix were compared with those for the ErCo2Mnx alloys.

Refrigerant Capacity and Magnetocaloric Effect on LaFe11.1Co0.8Si1.1BX Alloys

2011 ◽  
Vol 84-85 ◽  
pp. 667-670
Author(s):  
Guo Qiu Xie
Keyword(s):  
Magnetocaloric Effect ◽  
Room Temperature ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy ◽  
Field Change ◽  
Refrigerant Capacity ◽  
Structure Phase ◽  
Magnetic Field Change ◽  
Cubic Structure

In this paper, we report on the structure, magnetic properties and magnetocaloric effect in NaZn13-type LaFe11.1Co0.8Si1.1Bxalloys close to room temperature. The stable NaZn13cubic structure phase (space group isFm-3c) can easily obtained by annealing at 1080 °C for 225 hours. The maximal values of magnetic entropy change for LaFe11.1Co0.8Si1.1Bx(x=0.2, 0.25) were found to be 5.3 and 5.9 J/kg K at Curie temperature for a magnetic field change in 0-1.5 T, respectively. The calculated refrigerant capacity for a field change in 0–1.5 T is about 147 and 107 J/kg K, for LaFe11.1Co0.8Si1.1B0.2and LaFe11.1Co0.8Si1.1B0.25respectively, which is as larger as those of Gd(99.3%) alloy

Study of Magnetic Transition and Magnetocaloric Effect in La1-xSrxMnO3 (0.20≤ x ≤0.35) Compounds

2013 ◽  
Vol 378 ◽  
pp. 225-229 ◽  
Author(s):  
Yeong Seung Jeong ◽  
M.S. Anwar ◽  
Faheem Ahmed ◽  
Seung Rok Lee ◽  
Bon Heun Koo
Keyword(s):  
Curie Temperature ◽  
Magnetic Entropy Change ◽  
Perovskite Phase ◽  
Magnetic Transition ◽  
Entropy Change ◽  
Solid State Reaction Method ◽  
Magnetic Entropy ◽  
Conventional Solid State Reaction ◽  
Ionic Radii ◽  
The Difference

We report the magnetic transition and large magnetic entropy change in Sr doped lanthanum manganites. Polycrystalline La1-xSrxMnO3(0.20x0.35) samples were prepared using the conventional solid-state reaction method. The results of X-ray diffraction indicates perovskite phase without any impurity. The magnetic study has revealed that the Curie temperature is influenced by Sr-concentration. The doping of Sr at La site affects the Mn-O bond length and Mn-O-Mn bond angle due to the difference in their ionic radii, consequently, the Curie temperature changed. A large magnetic entropy change has been observed for La0.8Sr0.2MnO3sample, the value of the maximum entropy change (SMmax) increases from 1.42 to 2.74 J/kgK as magnetic field increases from 1 to 2.5 T. This investigation suggests that La1-xSrxMnO3can be used as a potential magnetic refrigeration material.

Study on Influence of Ca2+ Ions Doping at a Site on Magnetic Properties and Magnetocaloric Effect of Nominal Compositions La1.4Sr1.6-xCaxMn2O7

2015 ◽  
Vol 1120-1121 ◽  
pp. 406-413 ◽  
Author(s):  
Yun Zong ◽  
Di Kang
Keyword(s):  
Curie Temperature ◽  
Manganese Oxides ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Xrd Analysis ◽  
Layered Perovskite ◽  
Magnetic Entropy ◽  
Doping Amount ◽  
Space Group ◽  
Room Temperature Magnetic Refrigeration

Polycrystalline layered perovskite manganese oxides La1.4Sr1.6-xCaxMn2O7 (x=0,0.2,0.4,0.8,1.0,1.4,1.6) samples is prepared using solid state reaction.The XRD analysis shows that La1.4Sr1.6-xCaxMn2O7 (0 ≤ x ≤ 0.8) samples are Sr3Ti2O7-type tetragonal structure with space group I4/mmm and forms a layered perovskite structure; for the 1.0≤ x ≤1.6 series of samples the main phase is ABO3 type orthorhombic structure with space group Pbnm.For small amount of Ca2+ ion-doped sample (x= 0.2,0.4), induce serious Jahn-Teller(J-T) distortion of MnO6 octahedral.For a large number of doping (1.0≤ x ≤1.6) samples, ferromagnetic - paramagnetic transition occurs near the Curie temperature (Tc) from low to high temperatures.With increasing doping amount, the magnetization reached maximum at x=1.4 samples.Maximum magnetic entropy change of the three samples(x=1.0,1.4,1.6) reaches 0.84, 1.20 and 2.28 J kg-1 K-1 at 320,268 and 215K near the Curie temperature, respectively. The large magnetic entropy change effect under low magnetic field of the sample makes it an optimal candidate of room temperature magnetic refrigeration materials.

scholarly journals Extremely Large Magnetic Entropy Change of MnAs1-xSbx near Room Temperature

2002 ◽  
Vol 43 (1) ◽  
pp. 73-77 ◽  
Author(s):  
Hirofumi Wada ◽  
Kentaro Taniguchi ◽  
Yuji Tanabe
Keyword(s):  
Room Temperature ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy

Field Dependence of the Refrigerant Capacity for La0.6Ca0.4MnO3 Manganite

2009 ◽  
Vol 154 ◽  
pp. 163-168 ◽  
Author(s):  
R.A. Szymczak ◽  
Aleksandra Kolano-Burian ◽  
Roman Kolano ◽  
R. Puzniak ◽  
V.P. Dyakonov ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Curie Temperature ◽  
Statistical Model ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Relative Cooling Power ◽  
Cooling Power ◽  
Magnetic Entropy ◽  
Refrigerant Capacity ◽  
Jahn Teller

The magnetocaloric effect in La0.6Ca0.4MnO3 manganite has been investigated. The isothermal magnetization versus applied magnetic field at various temperatures in the vicinity of Curie temperature was measured, and the temperature dependence of magnetic entropy change was determined using Maxwell’s relation. This value is comparable to that in Gd. Nevertheless, the relative cooling power of La0.6Ca0.4MnO3 was shown to be considerably lower than that of Gd. The experimental results have been analyzed in frames of a phenomenological statistical model. This model considers explicitly Jahn-Teller interactions and allows prediction of the field dependences of the magnetic entropy change and the relative cooling power.

Room-temperature magnetic entropy change in La0.7 Sr0.3 Mn1-x Mx O3 (M = Al, Ti)

2007 ◽  
Vol 244 (12) ◽  
pp. 4570-4573 ◽  
Author(s):  
N. V. Dai ◽  
D. V. Son ◽  
S. C. Yu ◽  
L. V. Bau ◽  
L. V. Hong ◽  
...  
Keyword(s):  
Room Temperature ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy
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