Large Low-Field Reversible Magnetocaloric Effect in Itinerant-Electron Hf1-xTaxFe2 Alloys

First-order isostructural magnetoelastic transition with large magnetization difference and controllable thermal hysteresis are highly desirable in the development of high-performance magnetocaloric materials used for energy-efficient and environmental-friendly magnetic refrigeration. Here, we demonstrate large magnetocaloric effect covering the temperature range from 325 K to 245 K in Laves phase Hf1-xTaxFe2 (x = 0.13, 0.14, 0.15, 0.16) alloys undergoing the magnetoelastic transition from antiferromagnetic (AFM) state to ferromagnetic (FM) state on decreasing the temperature. It is shown that with the increase of Ta content, the nature of AFM to FM transition is gradually changed from second-order to first-order. Based on the direct measurements, large reversible adiabatic temperature change (ΔTad) values of 2.7 K and 3.4 K have been achieved under a low magnetic field change of 1.5 T in the Hf0.85Ta0.15Fe2 and Hf0.84Ta0.16Fe2 alloys with the first-order magnetoelastic transition, respectively. Such remarkable magnetocaloric response is attributed to the rather low thermal hysteresis upon the transition as these two alloys are close to intermediate composition point of second-order transition converting to first-order transition.

Reversibility of the Magnetocaloric Effect in the Bean-Rodbell Model

The applicability of magnetocaloric materials is limited by irreversibility. In this work, we evaluate the reversible magnetocaloric response associated with magnetoelastic transitions in the framework of the Bean-Rodbell model. This model allows the description of both second- and first-order magnetoelastic transitions by the modification of the η parameter (η<1 for second-order and η>1 for first-order ones). The response is quantified via the Temperature-averaged Entropy Change (TEC), which has been shown to be an easy and effective figure of merit for magnetocaloric materials. A strong magnetic field dependence of TEC is found for first-order transitions, having a significant increase when the magnetic field is large enough to overcome the thermal hysteresis of the material observed at zero field. This field value, as well as the magnetic field evolution of the transition temperature, strongly depend on the atomic magnetic moment of the material. For a moderate magnetic field change of 2 T, first-order transitions with η≈1.3−1.8 have better TEC than those corresponding to stronger first-order transitions and even second-order ones.

Underlying environmental factors and geomagnetic fields linked to 45 pilot whales Globicephala macrorhynchus stranding in Modung white beach, Indonesian coast on 19th February 2021

The reason whale and dolphin stranding is not fully understood and it is not linked to a standalone variable. Theories assume intertwined factors including sickness, underwater noise, navigational error, geographical features, the presence of predators, poisoning from pollution or algal blooms, geomagnetic field, and extreme weather are responsible to whale stranding. On 19th February 2021, a pod consists of 45 pilot whales Globicephala macrorhynchus was stranded in a remote 7050 m2 Modung white beach of Indonesian coast. This paper aims to assess the environmental factors that may be can explain and link to this stranding cases. Those factors include bathymetry, plankton cell density measured using MODIS, water sediment load measured using Sentinel 2 Bands 4,3,1, vessel traffic, precipitation (inch) and thunder (CAPE index J/kg), water salinity and temperature, and geomagnetic field (nT). The results show the water near stranding sites were shallow, has sediment load, high plankton density, warmer, receiving torrential rain prior stranding, having weak geomagnetic field and high total magnetic field change/year. The combination of those environmental covariates may influence the behavior, navigation, and echolocation of the said stranded pilot whale.

Detection of Early Stage of Fatigue Changes in Non-Alloy Steel Using Residual Magnetic Field Method

In this work, the fatigue of P265GH steel acc. to EN 10216-2 has been evaluated by measuring a residual magnetic field (RMF). During experiment the notched-specimen has been loaded with a servo-hydraulic uniaxial MTS test machine and a special magnetic sensor was applied. The measurement distribution of the residual magnetic field was performed in two axes. In the first stage of experiment the specimen was gradually loaded with quasi-static force in range of 0 to 16 kN (~ 0.7 Rm). The increase of strength of residual magnetic field was observed only from 0 to 8 kN, whereas in range 8 to 16 kN this effect was not noticed. In the second stage the controlled tensile fatigue test was performed (R = 0, Fmax = 16 kN). Up to 21k load cycles no changes to residual magnetic field were noticed. At 31k cycles the significant increase of amplitude of strength of residual magnetic field change was observed but visual inspection does not show any visible crack, while at 35k cycles crack was visible. It means that applied methodology allow to find the initiation of crack. The performed observation on SEM showed ductile fatigue of fracture.

Evaluation of Fatigue Damage in 304 Stainless Steel by Measuring Residual Magnetic Field

To demonstrate the feasibility of the passive magnetic NDT method for damage assessment of 304 austenitic stainless steel, the residual magnetic field change of the 304 stainless steel specimens under fatigue loads was investigated. The measurement was carried out using a fluxgate sensor and the magnetic characteristics were extracted for analysis of fatigue state. Then, the XRD test was carried out to investigate the mechanism of magnetic field changes and verify the reliability of the proposed method. The results show that the variation of the maximum gradient is consistent with the process of fatigue crack growth, which indicates that the fatigue damage can be estimated by residual magnetic field measuring. In future stage, how to distinguish the magnetic field changes derived from martensite transformation or stress magnetization effect will be investigated.

Multi-instrument Observations of Ion-Neutral Coupling in the Dayside Cusp

&lt;p&gt;Using data from the Scanning Doppler Imager, the Super Dual Auroral Radar Network, the EISCAT Svalbard Radar and an auroral all-sky imager, we examine an instance of F-region neutral winds which have been influenced by the presence of poleward moving auroral forms near the dayside cusp region. We observe a reduction in the time taken for the ion-drag force to re-orientate the neutrals into the direction of the convective plasma (on the order of minutes), compared to before the auroral activity began. Additionally, because the ionosphere near the cusp is influenced much more readily by changes in the solar wind via dayside reconnection, we observe the neutrals responding to an interplanetary magnetic field change within minutes of it occurring. This has implications on the rate that energy is deposited into the ionosphere via Joule heating, which we show to become dampened by the neutral winds.&lt;/p&gt;

Improvement of Pulse Voltage Generated by Wiegand Sensor Through Magnetic-Flux Guidance

Magnetization reversal in a Wiegand wire induces a pulse voltage in the pickup coil around the wire, called the Wiegand pulse. The Wiegand sensor features the Wiegand wire and the pickup coil. The amplitude and width of the Wiegand pulse are independent of the frequency of the magnetic-field change. The pulse is generated by the Wiegand sensor, which facilitates the use of the Wiegand sensor as a power supply for equipment without batteries. In order to meet the power consumption requirements, it is necessary to maximize the energy of the pulse signal from the Wiegand sensor, without changing the external field conditions. The distributions of the magnetic field generated from the applied magnet in air and in the Wiegand wire were simulated before the experiments. Simulation predicted an increase in the magnetic flux density through the center of the Wiegand wire. This study determined that the magnetic flux density through the center of the Wiegand wire, the position of the pickup coil, and the angle between the Wiegand sensor and the magnetic induction line were the main factors that affected the energy of a Wiegand pulse. The relationship between these factors and the energy of the Wiegand pulse were obtained.

Large and tunable magnetocaloric effect in gadolinium-organic framework: tuning by solvent exchange

Magnetic properties of three variants of MOF-76(Gd), {[Gd(BTC)(H2O)]·G}n (BTC = benzene-1,3,5-tricarboxylate, G = guest molecules) were investigated by static susceptibility, isothermal magnetization and specific heat capacity measurements. In the study we used as synthesized MOF-76(Gd)-DMF (1) (G = DMF = dimethylformamide), containing DMF molecules in the cavity system, compound MOF-76(Gd) (2), activated complex without solvents in the cavities and water exchanged sample MOF-76(Gd)-H2O (3). A pronounced change in the magnetic entropy was found near the critical temperature for all three compounds. It was shown, that magnetic entropy change depends on the solvatation of the MOF. The highest value entropy change, ΔSMpk(T) was observed for compound 2 (ΔSMpk(T) = 42 J kg−1 K−1 at 1.8 K for ΔH = 5 T). The ΔSMpk(T) for the compounds 1, 2 and 3 reached 81.8, 88.4 and 100% of the theoretical values, respectively. This suggests that in compound 3 Gd3+···Gd3+ antiferromagnetic interactions are decoupled gradually, and higher fields promote a larger decoupling between the individual spin centers. The observed entropy changes of compounds were comparable with other magnetic refrigerants proposed for low-temperature applications. To study the magnetothermal effect of 2 (the sample with largest −ΔSMpk), the temperature-dependent heat capacities (C) at different fields were measured. The value of magnetic entropy S obtained from heat capacities (39.5 J kg−1 K−1 at 1.8 K for an applied magnetic field change of 5 T) was in good agreement with that derived from the magnetization data (42 J kg−1 K−1 at 1.8 K).

Zn and P Alloying Effect in Sub-Rapidly Solidified LaFe11.6Si1.4 Magnetocaloric Plates

The occupation mechanism and magnetic transition behavior of trace Zn and P alloying in the sub-rapidly solidified LaFe11.6Si1.4 magnetocaloric plates were investigated. The LaFe11.6Si1.4, LaFe11.6Si1.4Zn0.03, and LaFe11.6Si1.4P0.03 plates were fabricated using the centrifugal casting method in the present work. Experimental results showed that both Zn and P elements were distributed in the La5Si3 and LaFeSi phases during sub-rapid solidification. After annealed at 1373 K for 72 h, the LaFe11.6Si1.4 plate underwent a second-order magnetic transition, while both the LaFe11.6Si1.4Zn0.03 and LaFe11.6Si1.4P0.03 plates underwent a first-order transition. In combination with X-ray diffraction results, it was proposed that both Zn and P atoms prefer to enter the 96i site substituting for FeII/Si atoms according to the density-functional reconstruction of crystallographic structure. The Zn addition led to a slight decrease in magnetic entropy change from 7.0 to 5.9 J/(kg⋅K), while the P addition strikingly enhanced this property to 31.4 J/(kg⋅K) under a magnetic field change of 3 T. The effective refrigeration capacity of the annealed LaFe11.6Si1.4P0.03 plate reached 189.9 J/kg.