Iodine Reaction

Author(s):  
ASBC Technical Committe
Keyword(s):  
1972 ◽  
Vol 3 (1) ◽  
pp. 52-59 ◽  
Author(s):  
Kiyoshi Kikukawa ◽  
Shun-ichi Nozakura ◽  
Shunsuke Murahashi

1931 ◽  
Vol 92 (2) ◽  
pp. 413-419
Author(s):  
John Field
Keyword(s):  

Energies ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 548
Author(s):  
Gabriela V. T. Kurban ◽  
Artur S. C. Rego ◽  
Nathalli M. Mello ◽  
Eduardo A. Brocchi ◽  
Rogério C. S. Navarro ◽  
...  

The sulfur–iodine thermochemical water-splitting cycle is a promising route proposed for hydrogen production. The decomposition temperature remains a challenge in the process. Catalysts, such as Pd supported on Al2O3, are being considered to decrease reaction temperatures. However, little is known regarding the kinetic behavior of such systems. In this work, zinc sulfate thermal decomposition was studied through non-isothermal thermogravimetric analysis to understand the effect of a catalyst within the sulfur–iodine reaction system context. The findings of this analysis were also related to a thermodynamic assessment. It was observed that the presence of Pd/Al2O3 modified the reaction mechanism, possibly with some intermediate reactions that were suppressed or remarkably accelerated. The proposed model suggests that zinc sulfate transformation occurred in two sequential stages without the Pd-based material. Activation energy values of 238 and 368 kJ.mol−1 were calculated. In the presence of Pd/Al2O3, an activation energy value of 204 kJ.mol−1 was calculated, which is lower than observed previously.


Genetics ◽  
1975 ◽  
Vol 80 (4) ◽  
pp. 711-714
Author(s):  
James H Meade ◽  
Herbert Gutz

ABSTRACT Colonies of Schizosaccharomyces pombe that contain ascospores (e.g., colonies of homothallic strains) turn black after treatment with iodine vapors. Heterothallic strains of S. pombe normally do not show this reaction. In experiments with the latter strains we found mutants which exhibit a positive iodine reaction though they do not contain ascospores. This phenotype is due to mutations in a new gene, vir1 (vegetative iodine reaction). The vir1 locus is not linked with the mating-type genes.—Strains of mating-type h-s are known not to give any spontaneous mating-type mutations. Mating-type mutations were also not found after treatment with nitrous acid.


1906 ◽  
Vol 11 (3) ◽  
pp. 304-332
Author(s):  
J. Barnicot
Keyword(s):  

Author(s):  
Jose Carlos Peraza Lizama ◽  
Carlos Martin Rubio Atoche ◽  
Alan Garcia Lira

This paper proposes a method of thermochemical-energy storage from magnesium sulfate recovered from salt ponds of sea water. The idea develops from a project originally thought to obtain magnesium oxide from a salt plant in the Yucatan Peninsula, Mexico. The new idea is based on the exploitation of the heat of decomposition of magnesium sulphate. In the traditional literature, closed-loop, reversible reaction is considered, whereas in this work, an open-loop is proposed; that is, sulphur dioxide is separated from the magnesium oxide before cooling down to 700°C; in this way, magnesium oxide is obtained by thermal decomposition, and at the same time, the high heat of decomposition is used to store thermal energy for electricity generation; magnesium oxide, sulfuric acid and hydrogen are co-products of the process if another iodine reaction cycle is considered. This second process is again a modification of an open-loop traditional process, to a closed-loop process where no sulphuric acid is required.


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