As early as 1904 it was shown by Eve that the passage of
γ
-rays through matter was accompanied by the emission of secondary rays somewhat less penetrating than the primary radiation. Experiments by Kleeman, Madsen and Florance led to the conclusion that the secondary radiation was not a fluorescent radiation but a scattered radiation since its quality appeared to be independent of the nature of the radiator. These early investigations prepared the way for an admirable series of experiments by J. A. Gray which established the main features of the scattering process, showing in particular that the smaller penetrating power of the scattered radiation is due to a change in quality accompanying the act of scattering. As is well-known, a simple quantum explanation of the phenomenon has been given by Compton, the smaller penetrating power of the scattered radiation being ascribed to the smaller momentum, and therefore longer wave-lengths of the deflected quanta. Recent developments of the quantum theory leave unchanged Compton’s relation between the change in wave-length and angle of scattering, since this relation involves only the assumption of the conservation of energy and momentum during the interaction of a quantum and a free electron. Experimental research since 1913 has in the main been directed towards establishing the angular distribution of intensity of the scattered radiation, and the variation with wave-length of the probability of interaction between a quantum and an electron. The experimental results lend strong support to the theoretical formulæ recently proposed by Klein and Nishina (
loc. cit.
), in fact it now appears probable that over the whole range of wave-lengths investigated, the new quantum mechanics leads to an accurate description of the interaction between a quantum and a free electron. From the standpoint of the older quantum theory all electrons could be regarded as “free” since the binding energy of even the K electrons in lead could be neglected in comparison with the energy of the quantum, which for the
γ
-rays usually investigated was between 1 and 2 million volts. The scattering power per electron (the scattering coefficient divided by the number of electrons per unit volume) of all substances should therefore be the same. The early measurements of J. A. Gray referred to above showed that this was roughly true of carbon, iron and lead over a limited angular range.