scholarly journals Diffusion-limited reactions of hard-core particles in one dimension

1999 ◽  
Vol 59 (2) ◽  
pp. 1996-2009 ◽  
Author(s):  
P.-A. Bares ◽  
M. Mobilia
1996 ◽  
Vol 464 ◽  
Author(s):  
Mark S. Feldman ◽  
Anna L. Lin ◽  
Raoul Kopelman

AbstractWe investigate the anomalous kinetics in one dimension of a diffusion limited catalytic trapping reaction, A + T → T, by measuring the oxidation of glucose. The reaction is carried out in a thin capillary tube, and the depletion of oxygen in the vicinity of the reaction front is monitored by the fluorescence of a Ru(II) dye. Theoretical results and simulations have predicted an asymptotic t1/2 dependence for the rate coefficient. We observe a depedence on t0.56, with what appears to be an asymptotic behavior approaching t1/2.


1988 ◽  
Vol 25 (04) ◽  
pp. 733-743 ◽  
Author(s):  
David Balding

One-dimensional, periodic and annihilating systems of Brownian motions and random walks are defined and interpreted in terms of sizeless particles which vanish on contact. The generating function and moments of the number pairs of particles which have vanished, given an arbitrary initial arrangement, are derived in terms of known two-particle survival probabilities. Three important special cases are considered: Brownian motion with the particles initially (i) uniformly distributed and (ii) equally spaced on a circle and (iii) random walk on a lattice with initially each site occupied. Results are also given for the infinite annihilating particle systems obtained in the limit as the number of particles and the size of the circle or lattice increase. Application of the results to the theory of diffusion-limited reactions is discussed.


1988 ◽  
Vol 25 (4) ◽  
pp. 733-743 ◽  
Author(s):  
David Balding

One-dimensional, periodic and annihilating systems of Brownian motions and random walks are defined and interpreted in terms of sizeless particles which vanish on contact. The generating function and moments of the number pairs of particles which have vanished, given an arbitrary initial arrangement, are derived in terms of known two-particle survival probabilities. Three important special cases are considered: Brownian motion with the particles initially (i) uniformly distributed and (ii) equally spaced on a circle and (iii) random walk on a lattice with initially each site occupied. Results are also given for the infinite annihilating particle systems obtained in the limit as the number of particles and the size of the circle or lattice increase. Application of the results to the theory of diffusion-limited reactions is discussed.


1996 ◽  
Vol 84 (3-4) ◽  
pp. 697-711 ◽  
Author(s):  
D. Arora ◽  
D. P. Bhatia ◽  
M. A. Prasad

1995 ◽  
Vol 09 (15) ◽  
pp. 895-919 ◽  
Author(s):  
DANIEL BEN-AVRAHAM

Diffusions limited reactions in confined geometries exhibit all aspects of nonequilibrium dynamics, such as anomalous kinetics, self-organization and dynamical phase transitions, and have therefore been the subject of extensive research in recent years. In this paper we review the method of interparticle distribution functions (IPDF) which was originally introduced for deriving the exact kinetics of the diffusion-limited coalescence process, A+A→A, in one dimension. We explain the IPDF method and review variants of the coalescence model which can be solved exactly through this technique. We then consider strategies for approximations based on the IPDF method and review applications to coalescence with finite reaction rates (away from the strictly diffusion-controlled regime), many-body reactions (nA→mA), and the contact process. We conclude with a discussion of open, interesting problems and possible ways to their solution.


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