scholarly journals Prospective Role of Multicenter Bonding for Efficient and Selective Hydrogen Transport

2010 ◽  
Vol 105 (4) ◽  
Author(s):  
Daniele Stradi ◽  
Francesc Illas ◽  
Stefan T. Bromley
2018 ◽  
Vol 20 (28) ◽  
pp. 19098-19109 ◽  
Author(s):  
Z. Blossom Yan ◽  
Alan P. Young ◽  
Gillian R. Goward

Perfluorosulfonic acid (PFSA) materials have been used in polymer electrolyte membrane fuel cells (PEMFCs) as electrolyte materials due to their mechanical durability and high proton conductivity.


1993 ◽  
Vol 47 (15) ◽  
pp. 9993-9996 ◽  
Author(s):  
W. B. Jackson ◽  
P. V. Santos ◽  
C. C. Tsai
Keyword(s):  

2021 ◽  
Author(s):  
Jan Hempelmann ◽  
Peter C. Müller ◽  
Christina Ertural ◽  
Richard Dronskowski

Layered phase-change materials in the Ge–Sb–Te-system are widely used in data storage and are the subject of intense research to understand the elusive quantum-chemical origin of their unique properties. To uncover the nature of the underlying periodic wavefunction, we study the interacting atomic orbitals including their phase information as revealed by crystal orbital bond index (COBI) and fragment crystal orbital (FCO) analysis. In full accord with previous and also new findings based on projected force constants (pFC), we demonstrate the decisive role of multicenter bonding along straight atomic connectivities such as Te–Ge–Te and Te–Sb–Te. While the here found multicenter bonding resembles well-established three-center four-electron bonding in molecules, its solid-state manifestation beyond a molecular motif leads to distinct longe-range consequences, thus serving to contextualize the aforementioned material properties usually termed “metavalent”. For example, we suggest multicenter bonding to be the origin of their astonishing bond-breaking and also phase-change behavior. As a hole-in-one, multicenter bonding immediately explains the too small “van der Waals” gaps between individual layers since multicenter bonding forces these gaps to shrink below the nonbonding Te–Te distances.


1998 ◽  
Vol 43 (1) ◽  
pp. 114-116 ◽  
Author(s):  
A. V. Samsonov ◽  
A. Yu. Koren’kov ◽  
I. E. Gabis ◽  
A. A. Kurdyumov
Keyword(s):  

1952 ◽  
Vol 51 (3) ◽  
pp. 375-379 ◽  
Author(s):  
B. P. Eddy ◽  
M. Ingram ◽  
L. W. Mapson

CORROSION ◽  
10.5006/3961 ◽  
2022 ◽  
Author(s):  
Lisa Blanchard ◽  
Kasra Sotoudeh ◽  
James Hesketh ◽  
Gareth Hinds ◽  
Hongbiao Dong

The quantified microstructural analysis carried out on a wrought and a hot isostatically-pressed (HIP) UNS S31803 duplex stainless steel (DSS) in the Part 1 publication of this study 1, established the significance of the three-dimensional (3D) distribution and morphology/geometry of the ferrite and austenite phases on hydrogen transport through two DSS product forms. This paper is a follow-on to Part 1, and focuses on the role of the other two key, interrelated components of hydrogen-induced stress cracking (HISC): stress/strain, and hydrogen. For this purpose, experimental hydrogen permeation measurements, and environmental fracture toughness testing (i.e. J R-curve testing) using conventional and non-standard single-edge notched bend test specimens were used. These particularly enabled interpretation of the hydrogen permeation and transport test data, and evaluation of suitability of environmental fracture toughness test methods for the assessment of resistance to HISC in DSSs. The latter is discussed, both from laboratory and component integrity perspectives, in the context of the findings from the 3D microstructural characterisation of the two phases, the role of stress raisers and their severity, and hydrogen transport through the bulk and from the surface.


JAMA ◽  
1966 ◽  
Vol 195 (12) ◽  
pp. 1005-1009 ◽  
Author(s):  
D. J. Fernbach
Keyword(s):  

JAMA ◽  
1966 ◽  
Vol 195 (3) ◽  
pp. 167-172 ◽  
Author(s):  
T. E. Van Metre

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