scholarly journals Electronic Entanglement in Late Transition Metal Oxides

2012 ◽  
Vol 109 (18) ◽  
Author(s):  
Patrik Thunström ◽  
Igor Di Marco ◽  
Olle Eriksson
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Late Transition Metal ◽  
Late Transition

GW approximation study of late transition metal oxides: Spectral function clusters around Fermi energy as the mechanism behind smearing in momentum density

2016 ◽  
Vol 30 (14) ◽  
pp. 1650162
Author(s):  
S. M. Khidzir ◽  
K. N. Ibrahim ◽  
W. A. T. Wan Abdullah
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Fermi Energy ◽  
Momentum Density ◽  
The Self ◽  
Late Transition Metal ◽  
Gw Approximation ◽  
Self Energy ◽  
Late Transition

Momentum density studies are the key tool in Fermiology in which electronic structure calculations have proven to be the integral underlying methodology. Agreements between experimental techniques such as Compton scattering experiments and conventional density functional calculations for late transition metal oxides (TMOs) prove elusive. In this work, we report improved momentum densities of late TMOs using the GW approximation (GWA) which appears to smear the momentum density creating occupancy above the Fermi break. The smearing is found to be largest for NiO and we will show that it is due to more spectra surrounding the NiO Fermi energy compared to the spectra around the Fermi energies of FeO and CoO. This highlights the importance of the positioning of the Fermi energy and the role played by the self-energy term to broaden the spectra and we elaborate on this point by comparing the GWA momentum densities to their LDA counterparts and conclude that the larger difference at the intermediate level shows that the self-energy has its largest effect in this region. We finally analyzed the quasiparticle renormalization factor and conclude that an increase of electrons in the [Formula: see text]-orbital from FeO to NiO plays a vital role in changing the magnitude of electron correlation via the self-energy.

Electronic Structures and Gas-Phase Reactivities of Cationic Late-Transition-Metal Oxides

1994 ◽  
Vol 116 (23) ◽  
pp. 10734-10741 ◽  
Author(s):  
Andreas Fiedler ◽  
Detlef Schroeder ◽  
Sason Shaik ◽  
Helmut Schwarz
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Gas Phase ◽  
Transition Metal Oxides ◽  
Electronic Structures ◽  
Late Transition Metal ◽  
Late Transition

Surface Chemistry of Late Transition Metal Oxides

2013 ◽  
Vol 113 (6) ◽  
pp. 4164-4215 ◽  
Author(s):  
Jason F. Weaver
Keyword(s):  
Transition Metal ◽  
Surface Chemistry ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Late Transition Metal ◽  
Late Transition

Alkane Activation and Oxidation on Late-Transition-Metal Oxides: Challenges and Opportunities

ACS Catalysis ◽  
2021 ◽  
pp. 4682-4703
Author(s):  
R. Martin ◽  
M. Kim ◽  
A. Asthagiri ◽  
J. F. Weaver
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Late Transition Metal ◽  
Alkane Activation ◽  
Challenges And Opportunities ◽  
Late Transition

scholarly journals Intertwined density waves in a metallic nickelate

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Junjie Zhang ◽  
D. Phelan ◽  
A. S. Botana ◽  
Yu-Sheng Chen ◽  
Hong Zheng ◽  
...  
Keyword(s):  
Fermi Surface ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Degrees Of Freedom ◽  
Density Wave ◽  
Single Layer ◽  
Late Transition Metal ◽  
Density Waves ◽  
Paramagnetic Metal ◽  
Late Transition

AbstractNickelates are a rich class of materials, ranging from insulating magnets to superconductors. But for stoichiometric materials, insulating behavior is the norm, as for most late transition metal oxides. Notable exceptions are the 3D perovskite LaNiO3, an unconventional paramagnetic metal, and the layered Ruddlesden-Popper phases R4Ni3O10, (R = La, Pr, Nd). The latter are particularly intriguing because they exhibit an unusual metal-to-metal transition. Here, we demonstrate that this transition results from an incommensurate density wave with both charge and magnetic character that lies closer in its behavior to the metallic density wave seen in chromium metal than the insulating stripes typically found in single-layer nickelates like La2-xSrxNiO4. We identify these intertwined density waves as being Fermi surface-driven, revealing a novel ordering mechanism in this nickelate that reflects a coupling among charge, spin, and lattice degrees of freedom that differs not only from the single-layer materials, but from the 3D perovskites as well.

HREM Study of electron-induced surface radiation damage in ReO3

1991 ◽  
Vol 49 ◽  
pp. 636-637
Author(s):  
R. Ai ◽  
H.-J. Fan ◽  
L. D. Marks
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Metal Oxides ◽  
Electron Irradiation ◽  
Transition Metal Oxides ◽  
Carbon Film ◽  
Transition Metal Ions ◽  
Surface Radiation ◽  
Valence Transition ◽  
Electron Microscopes

It has been known for a long time that electron irradiation induces damage in maximal valence transition metal oxides such as TiO2, V2O5, and WO3, of which transition metal ions have an empty d-shell. This type of damage is excited by electronic transition and can be explained by the Knoteck-Feibelman mechanism (K-F mechanism). Although the K-F mechanism predicts that no damage should occur in transition metal oxides of which the transition metal ions have a partially filled d-shell, namely submaximal valence transition metal oxides, our recent study on ReO3 shows that submaximal valence transition metal oxides undergo damage during electron irradiation.ReO3 has a nearly cubic structure and contains a single unit in its cell: a = 3.73 Å, and α = 89°34'. TEM specimens were prepared by depositing dry powders onto a holey carbon film supported on a copper grid. Specimens were examined in Hitachi H-9000 and UHV H-9000 electron microscopes both operated at 300 keV accelerating voltage. The electron beam flux was maintained at about 10 A/cm2 during the observation.

Problems with oxygen analysis in the system MgO-Al2O3-SiO2 with the electron microprobe

1992 ◽  
Vol 50 (2) ◽  
pp. 1624-1625
Author(s):  
Michel Fialin ◽  
Guy Rémond
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Electrostatic Charge ◽  
Carbon Layer ◽  
Sample Holder ◽  
Rock Matrix ◽  
Electrical Discharges ◽  
Thin Carbon ◽  
Beam Instabilities

Oxygen-bearing minerals are generally strong insulators (e.g. silicates), or if not (e.g. transition metal oxides), they are included within a rock matrix which electrically isolates them from the sample holder contacts. In this respect, a thin carbon layer (150 Å in our laboratory) is evaporated on the sections in order to restore the conductivity. For silicates, overestimated oxygen concentrations are usually noted when transition metal oxides are used as standards. These trends corroborate the results of Bastin and Heijligers on MgO, Al2O3 and SiO2. According to our experiments, these errors are independent of the accelerating voltage used (fig.l).Owing to the low density of preexisting defects within the Al2O3 single-crystal, no significant charge buildup occurs under irradiation at low accelerating voltage (< 10keV). As a consequence, neither beam instabilities, due to electrical discharges within the excited volume, nor losses of energy for beam electrons before striking the sample, due to the presence of the electrostatic charge-induced potential, are noted : measurements from both coated and uncoated samples give comparable results which demonstrates that the carbon coating is not the cause of the observed errors.

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