The bis(ethylenedithio)tetrathiafulvalene-based ionic charge-transfer complex with 2,3-dichloro-5,6-dicyano-p-benzoquinone
2013 ◽
Vol 69
(4)
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pp. 400-402
Keyword(s):
In the ionic charge-transfer (CT) complex composed of bis(ethylenedithio)tetrathiafulvalene (ET) and 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), C10H8S8·C8Cl2N2O2, the donor and acceptor molecules both form centrosymmetric dimers associated by strong face-to-face π–π interactions. The disordered DDQ molecules form a one-dimensional π-stacked column, while the ET molecules form a two-leg ladder through additional short S...S contacts between adjacent π–π-bonded dimers. The crystal structure of ET–DDQ revealed in this study will provide a valuable example of the two-leg spin ladder system, which has rarely been reported for ET-based CT complexes.
2003 ◽
pp. 546-548
Keyword(s):
1974 ◽
Vol 29
(6)
◽
pp. 880-887
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Keyword(s):
2015 ◽
Vol 7
(36)
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pp. 20280-20284
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Keyword(s):
1994 ◽
Vol 135
(1-2)
◽
pp. 196-198
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Keyword(s):
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2000 ◽
Vol 73
(10)
◽
pp. 2231-2235
2019 ◽
Vol 23
(10)
◽
pp. 1149-1157
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