A new approach to molecular synthesis and crystal growth of one-dimensional organic charge transfer complex TTF-TCNQ

1994 ◽  
Vol 135 (1-2) ◽  
pp. 196-198 ◽  
Author(s):  
Devendra Puri Goswami ◽  
M.L. Kalra
Nature ◽  
1963 ◽  
Vol 197 (4865) ◽  
pp. 375-375 ◽  
Author(s):  
H. SCOTT ◽  
H. UR ◽  
M. M. LABES

Author(s):  
Yuki Nakagawa ◽  
Yukihiro Takahashi ◽  
Jun Harada ◽  
Tamotsu Inabe

In the ionic charge-transfer (CT) complex composed of bis(ethylenedithio)tetrathiafulvalene (ET) and 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), C10H8S8·C8Cl2N2O2, the donor and acceptor molecules both form centrosymmetric dimers associated by strong face-to-face π–π interactions. The disordered DDQ molecules form a one-dimensional π-stacked column, while the ET molecules form a two-leg ladder through additional short S...S contacts between adjacent π–π-bonded dimers. The crystal structure of ET–DDQ revealed in this study will provide a valuable example of the two-leg spin ladder system, which has rarely been reported for ET-based CT complexes.


2008 ◽  
Vol 43 (6) ◽  
pp. 683-688 ◽  
Author(s):  
R. Bharathikannan ◽  
A. Chandramohan ◽  
M. A. Kandhaswamy ◽  
J. Chandrasekaran ◽  
R. Renganathan ◽  
...  

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