Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN
3)imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN
3))copper(II) perchlorate
2019 ◽
Vol 75
(5)
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pp. 547-551
Keyword(s):
In the crystal structure of the title complex, [CuCl(C17H24N8)]ClO4, the copper(II) metal exhibits an N4Cl pentacoordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methylimidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Intermolecular interactions take place at two of the 1-methyl-imidazole rings in the form of parallel-displaced π–π stacking interactions forming chains parallel to the a axis. Three O atoms of the perchlorate anion are rotationally disordered between two orientations with occupancies of 0.5.
2014 ◽
Vol 70
(4)
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pp. 359-363
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2014 ◽
Vol 70
(7)
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pp. 718-721
2001 ◽
Vol 56
(6)
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pp. 521-525
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2007 ◽
Vol 63
(11)
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pp. m2753-m2753
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Keyword(s):
2016 ◽
Vol 72
(2)
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pp. 164-169
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Keyword(s):
2015 ◽
Vol 71
(2)
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pp. m38-m39
2006 ◽
Vol 62
(7)
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pp. m1471-m1473
Keyword(s):
2020 ◽
Vol 76
(9)
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pp. 1539-1542
2012 ◽
Vol 67
(3)
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pp. 197-203
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2019 ◽
Vol 75
(7)
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pp. 1061-1064