Di-μ-chlorido-bis{[2-(di-tert-butylphosphanyl)biphenyl-3-yl-κ2C3,P]palladium(II)} dichloromethane disolvate
2013 ◽
Vol 69
(2)
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pp. m86-m86
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Keyword(s):
The asymmetric unit of the title compound, [Pd2Cl2(C20H26P)2]·2CH2Cl2, contains one half-molecule of the palladium complex and a dichloromethane solvent molecule. In the complex, two PdIIatoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the PdIIatom and a cyclometallated four-membered ring. The Pd2Cl2unit is located about an inversion center. The planes of the rings of the biphenyl system make a dihedral angle of 66.36 (11)°.
2012 ◽
Vol 68
(6)
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pp. m717-m718
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Keyword(s):
2015 ◽
Vol 71
(12)
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pp. m261-m262
Keyword(s):
2013 ◽
Vol 69
(11)
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pp. o1666-o1666
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Keyword(s):
2017 ◽
Vol 73
(8)
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pp. 1162-1166
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2014 ◽
Vol 70
(8)
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pp. 828-832