Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvate
2013 ◽
Vol 69
(12)
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pp. m676-m677
Keyword(s):
The title complex, [Ti2Cl4{CH3C(CH2O)2(CH2OH)}2], lies across a centre of symmetry with a diethyl ether solvent molecule hydrogen bonded to the –CH2OH groups on either side of it. The TiIVatom is coordinated in a distorted octahedral geometry by a tripodal ligand and two terminal chloride atoms. There are three coordination modes for the tripodal ligand distinguishable on the basis of their very different Ti—O bond lengths. For the terminal alkoxo ligand, the Ti—O distance is 1.760 (1) Å, the asymmetric bridge system has Ti—O bond lengths of 1.911 (1) and 2.048 (1) Å. The Ti—O bond length for the alcohol O atom is the longest at 2.148 (1) Å.
2014 ◽
Vol 70
(3)
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pp. m96-m97
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2014 ◽
Vol 70
(5)
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pp. 508-511
2012 ◽
Vol 68
(8)
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pp. m1055-m1055
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2014 ◽
Vol 70
(7)
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pp. m278-m279
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2016 ◽
Vol 72
(1)
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pp. 17-20
2012 ◽
Vol 68
(6)
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pp. m801-m802
2007 ◽
Vol 63
(11)
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pp. m2751-m2751
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2007 ◽
Vol 63
(11)
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pp. m2752-m2752
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2012 ◽
Vol 68
(6)
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pp. m830-m831
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